C_(f)/C复合材料的ZrB_(2)-SiC基抗氧化涂层研究进展  

Research Progress of ZrB_(2)-SiC Based Anti-oxidation Coatings of C_(f)/C Composites

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作  者:方要华 张治 王永新 彭杰 张海军[1] 刘江昊[1] Fang Yaohua;Zhang Zhi;Wang Yongxin;Peng Jie;Zhang Haijun;Liu Jianghao(The State Key Laboratory of Refractories and Metallurgy,Wuhan University of Science and Technology,Wuhan 430081,China)

机构地区:[1]武汉科技大学省部共建耐火材料与冶金国家重点实验室,湖北武汉430081

出  处:《稀有金属材料与工程》2024年第11期3259-3270,共12页Rare Metal Materials and Engineering

基  金:国家自然科学基金(52372030,52232002,52272021,52072274)。

摘  要:C_(f)/C复合材料具有低密度、高热导率、优秀的抗侵蚀性能和良好的抗热震性能等优点,在高超声速飞行器、飞机刹车盘和火箭喷管等高端结构材料领域具有广阔的应用前景。然而,由于C_(f)/C复合材料的高氧化敏感性,其易产生严重的化学烧蚀和服役性能退化等问题。在C_(f)/C复合材料表面制备ZrB_(2)-SiC基超高温陶瓷基涂层是上述问题的最有效解决方案。基于此,本文综述了ZrB_(2)-SiC基超高温陶瓷涂层的组成/结构设计和抗氧化性能及强化机理的研究现状,系统地分析了ZrB_(2)-SiC基陶瓷涂层常用制备方法的原理和优缺点,并且对本领域研究的未来发展方向进行了展望。Owing to their outstanding properties including low density,high thermal conductivity,good ablation and thermal-shock resistances,C_(f)/C composites have great potentials in various high-end structural application fields such as hypersonic aircraft,aircraft braking systems and rocket nozzles.However,the high oxidation sensitivity of C_(f)/C composites generally causes some severe problems including serious chemical ablation and significant degradation of service performances.To address these problems,the preparation of ZrB_(2)-SiC-based ultra-high temperature ceramics(UHTCs)coatings on the surface of C_(f)/C composites is the most effective solution so far.Consequently,this paper reviewed the recent progress in the topics of compositional/microstructural modifications of ZrB_(2)-SiC-based coatings,their oxidation resistances and enhancement mechanisms.Moreover,the principles as well as advantages/disadvantages of popular preparation methods of ZrB_(2)-SiC-based ceramic coatings were summarized.Based on this,the prospects of the promising directions of research and the technique development of this field were forecasted.

关 键 词:C_(f)/C复合材料 ZrB_(2)-SiC基陶瓷涂层 抗氧化性能 组成/结构设计 

分 类 号:TQ174.758.16[化学工程—陶瓷工业]

 

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