Inducing photocarrier separation via 3D porous faveolate cross-linked carbon to enhance photothermal/pyroelectric property  

作　　者：Meng Li Jingxue Sun Gang Chen Shuang Wang Shunyu Yao 

机构地区：[1]MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage,School of Chemistry and Chemical Engineering,Harbin Institute of Technology,Harbin 150001,China

出　　处：《Advanced Powder Materials》2022年第3期88-98,共11页先进粉体材料（英文）

摘　　要：The CdS/Bi_(2)S_(3) supported three-dimensional(3D)porous faveolate carbon structure(CdS/Bi_(2)S_(3)@C)composite photocatalyst was constructed.Bi_(2)S_(3) nanoparticles are regarded as photothermal agents and pyroelectric materials to absorb near infrared light(NIR)and convert it into heat.3D porous faveolate of carbon acts as incubator to reduce heat loss and optimize photothermal effects.There is a greater fluctuating temperature difference(ΔΤ)between photothermal effect of Bi_(2)S_(3) and cold photocatalytic system.This enhances the pyroelectric effect that Bi_(2)S_(3) undergoes spontaneous polarization and releases the surface charge.Therefore,the separation of electrons and holes in the CdS photocatalyst can be induced.The COMSOL simulation results show that,the higher pyroelectric potential producted by largerΔΤis more favorable to the photocatalytic process.The hydrogen evolution rate of CdS/Bi_(2)S_(3)@C photocatalyst can reach 5.88 mmol·g^(-1)·h^(-1) with excellent cycle stability.

关 键 词：3D porous faveolate structure INCUBATOR Photothermal/pyroelectric Spontaneous polarization COMSOL simulation 

分 类 号：TB3[一般工业技术—材料科学与工程]