电催化下醛酮类物质羟醛缩合制备航油前驱体研究进展  

Preparation of Aviation Oil Precursor by Aldol Condensation of Aldehydes and Ketones Under Electrocatalysis

作　　者：王梦艳 王贻诚 尹勇军 王琼 Wang Mengyan;Wang Yicheng;Yin Yongjun;Wang Qiong(Guangxi Key Lab of Clean Pulp&Papermaking and Pollution Control,School of Light Industry and Food Engineering,Guangxi University,Guangxi,530004;Institute of Zhejiang University-Quzhou,Zhejiang,324000)

机构地区：[1]广西大学轻工与食品工程学院广西清洁制浆造纸及污染控制重点实验室,广西530004 [2]浙江大学衢州研究院,浙江324000

出　　处：《当代化工研究》2024年第22期27-29,共3页Modern Chemical Research

摘　　要：在催化领域,通过电催化技术催化醛酮类物质羟醛缩合制备航空燃油前驱体是一种绿色环保、快速高效的方法,同时可以降低反应能源成本、易于扩大反应规模。生物质衍生物糠醛具有一系列官能团,是一种丰富的平台化合品,可以转化为各种化学品和燃料。近年来,与传统热催化相比,绿色可持续的电催化技术更有吸引力。从物质间的偶联反应、催化剂的影响、电化学反应器、反应机理几个方面综述了近年来醛酮类物质电催化转化的研究进展。最后,强调了当前电催化生产航油前驱体发展的前景并提出了合理的建议。In the field of catalysis,using electrocatalytic technology to catalyze the aldol condensation of aldehydes and ketones to prepare aviation fuel precursors is a green,environmentally friendly,fast,and efficient method that can reduce reaction energy costs and facilitate the expansion of reaction scale.Biomass derivative furfural has a series of functional groups and is a rich platform compound that can be converted into various chemicals and fuels.In recent years,green and sustainable electrocatalytic technology has become more attractive compared to traditional thermal catalysis.This article reviews the research progress in the electrocatalytic conversion of aldehydes and ketones in recent years from the aspects of coupling reactions between substances,the influence of catalysts,electrochemical reactors,and reaction mechanisms.Finally,we emphasized the prospects for the development of precursors for electrocatalytic production of aviation oil and put forward reasonable suggestions.

关 键 词：生物质 醛酮类物质 糠醛 电解催化 

分 类 号：O62[理学—有机化学]