A review of the preparation process and anode stabilization strategies of Zn microbatteries  

作　　者：Xin Guo Sajian Wu Xiaojun Guo Dexu Zheng Yan Zhu Jishuang Liu Xinxin Xing Haoxiang Zhang Shengzhong(Frank)Liu 

机构地区：[1]Dalian National Laboratory for Clean Energy,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China [2]Center of Materials Science and Optoelectronics Engineering,University of Chinese Academy of Sciences,Beijing 100049,China [3]CNNP Optoelectronics Technology(Shanghai)Co.,Ltd.,Shanghai 201306,China [4]Key Laboratory of Applied Surface and Colloid Chemistry,Ministry of Education,Shaanxi Key Laboratory for Advanced Energy Devices,Shaanxi Engineering Lab for Advanced energy Technology,Institute for Advanced Energy Materials,School of Materials Science and Engineering,Shaanxi Normal University,Xi’an 710119,China

出　　处：《iEnergy》2024年第1期12-27,共16页电力能源汇刊（英文）

基　　金：supported by the National Key Research Program of China(2022YFE0138100);the National Nature Science Foundation of China(52350710208);the Cooperation Foundation of Yulin University and Dalian National Laboratory for Clean Energy(YLU-DNL fund 2022011);the National Nature Science Foundation of China(22279140,U20A20252,U21A20102,62174103);the Innovation Fund Project of Dalian Institute of Chemical Physics(DICP I202025,DICP I202032);the Cooperation Foundation of Dalian National Laboratory for Clean Energy of the Chinese Academy of Sciences(DNL202015);the Natural Science Foundation of Liaoning Province(2021-MS-016);the Youth Science and Technology Star Project of Dalian(2021RQ121);the 111 Project(B1404),the Project of Knowledge Innovation Engineering(Y261261606);the Fundamental Research Funds for the Central Universities(GK202103106);the Shanxi Science and Technology Department(20201101012).

摘　　要：As a burgeoning energy storage technology,Zn microbatteries(ZMBs)exhibit expansive potential for applications.This article initially presents a method for fabricating ZMBs utilizing interdigitated electrodes,employing advanced techniques such as 3D printing,screen printing,laser etching,and electrodeposition.These methodologies play a crucial role in mitigating anode-related issues,consequently enhancing battery performance.Subsequently,the challenges encountered by ZMBs anodes,including dendrite formation,corrosion passivation,hydrogen evolution,and Zn cycle exfoliation,are thoroughly examined.Lastly,a comprehensive strategy for stabilizing the anode is delineated,encompassing anode material selection,anode structure construction,interface engineering,and electrolyte optimization.In essence,the preparation and fine-tuning of ZMBs present ongoing challenges.With continued research and development efforts,it is anticipated that ZMBs will attain efficient,stable,and secure performance on the microscale,offering enduring and dependable energy solutions for applications in miniature electronic devices and wearable technology.

关 键 词：Zinc-ion MICROBATTERIES FLEXIBILITY 

分 类 号：TG6[金属学及工艺—金属切削加工及机床]