Manipulation of the through-space interactions in diphenylmethane  

作　　者：Weihao Tu Zuping Xiong Ziteng Zhang Jianyu Zhang Lei Wang Yuan Xie Yipu Wang Haoke Zhang Jing Zhi Sun Ben Zhong Tang 

机构地区：[1]MOE Key Laboratory of Macromolecular Synthesis and Functionalization,Department of Polymer Science and Engineering,Zhejiang University,Hangzhou,China [2]ZJU-Hangzhou Global Scientific and Technological Innovation Center,Hangzhou,China [3]Department of Chemistry,Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction,The Hong Kong University of Science and Technology,Hong Kong,China [4]Center for AIE Research,College of Materials Science and Engineering,Shenzhen University,Shenzhen,China [5]School of Science and Engineering,Shenzhen Institute of Aggregate Science and Technology,The Chinese University of Hong Kong,Shenzhen,China

出　　处：《Smart Molecules》2023年第2期45-53,共9页智能分子（英文）

基　　金：the National Science Foundation of China(22205197);the project funded by China Postdoctoral Science Foundation(2022M712721);the Youth Talent Excellence Program of ZJU-Hangzhou Global Scientific and Technological Innovation Center.

摘　　要：Through-space interaction(TSI)has been proven to play an important role in the newly emerging clusteroluminescence(CL)phenomenon.However,it is still a big challenge to manipulate the TSI at the molecular level due to the unclear relationship between the non-conjugated structure and TSI properties.Herein,the TSI in diphenylmethane is manipulated by breaking its symmetric structures and changing the isolated subunits.Finally,the CL wavelength and efficiency of diphenylmethane are successfully regulated at the aggregate state.

关 键 词：clusteroluminescence DIPHENYLMETHANE PHOTOPHYSICS through-space interactions 

分 类 号：TM6[电气工程—电力系统及自动化]