[2]Biphenyl-extended pillar[6]arene functionalized silver nanoparticles for catalysis and label-free detection  

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作  者:Dongxia Li Gengxin Wu Xin Wang Jia-Rui Wu Ying-Wei Yang 

机构地区:[1]International Joint Research Laboratory of Nano-Micro Architecture Chemistry,College of Chemistry,Jilin University,Changchun,China [2]Key Laboratory of Automobile Materials of Ministry of Education and School of Materials Science and Engineering,Jilin University,Changchun,China

出  处:《Smart Molecules》2023年第3期113-119,共7页智能分子(英文)

基  金:the National Natural Science Foundation of China(Nos.52173200 and 22201096);the Natural Science Foundation of Jilin Province(No.20230101052JC);the Fundamental Research Funds for the Central Universities(No.2022-JCXK-13)for financial support.

摘  要:Synthetic macrocycles have served as principal tools for supramolecular chemistry since their establishment,and the investigation of macrocycles-aided organicinorganic hybrid nanomaterials has also attracted broad interest in chemistry and material communities during the past decade owing to their widespread applications in optical sensing,catalytic degradation,biomedicine,and other related fields.Herein,a new class of silver nanoparticles(AgNPs)modified by anionic watersoluble[2]biphenyl-extended pillar[6]arene(WBpP6),namely WBpP6-AgNPs,is designed and synthesized through a facile one-pot method.WBpP6-AgNPs with good dispersion and stability exhibit efficient catalytic properties toward the hydrogenation of a series of aromatic nitro compounds and also show good performance in label-free detection toward diquat.

关 键 词:CATALYSIS host-guest chemistry macrocyclic chemistry organic-inorganic hybrid nanomaterials supramolecular chemistry 

分 类 号:O62[理学—有机化学]

 

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