Enhanced energy storage characteristics of the epoxy film with rigid phenyl-flexible etherified methylene chains  

作　　者：Zhengdong Wang Mengli Li Botao Liu Ganqiu Yang Meng Luo Tong Zhang Ling Li Yonghong Cheng Zirui Jia Guanglei Wu 

机构地区：[1]School of Mechanical and Electrical Engineering,Xi’an University of Architecture and Technology,Xi’an 710055,China [2]State Key Laboratory of Electrical Insulation and Power Equipment,Xi’an Jiaotong University,Xi’an 710049,China [3]Institute of Materials for Energy and Environment,State Key Laboratory of Bio-Fibers and Eco-Textiles,College of Materials Science and Engineering,Qingdao University,Qingdao 266071,China

出　　处：《Journal of Materials Science & Technology》2024年第16期12-22,共11页材料科学技术（英文版）

基　　金：funding from the National Natural Science Foundation of China(nos.52307028,52301192,and 52377026);State Key Laboratory of Electrical Insulation and Power Equipment Open Project(no.EIPE22210);Shaanxi Provincial Science and Technology Department Youth Foundation(no.2022JQ-300);Shaanxi Province Industry-University-Research Collaborative Innovation Plan(no.2023YFBT-45-02);Taishan Scholars and Young Experts Program of Shandong Province(no.tsqn202103057);the Qingchuang Talents Induction Program of Shandong Higher Education Institution(Research and Innovation Team of Structural-Functional Polymer Composites);Special Financial of Shandong Province(Structural Design of High-efficiency Electromagnetic Wave-absorbing Composite Materials and Construction of Shandong Provincial Talent Teams)。

摘　　要：The introduction of highly polarized flexible segments into polymer molecular chains is an effective means to improve the dielectric constant and mechanical flexibility of polymers,which is important for improving the energy storage characteristics and applicability for the roll-to-roll process of metallic film capacitors.However,the introduction of flexible segments may adversely affect the heat resistance of polymer materials,which limits their application at high working temperatures.In this work,we have prepared a novel epoxy film with excellent comprehensive properties by introducing rigid phenyl and flexible etherified methylene side chains.For instance,the optimal epoxy film showed an energy storage density of 7.06 J cm^(-3)and 85%charge-discharge efficiency at room temperature and 420 kV mm^(-1).At 200 kV mm^(-1)and 110°C,a working condition for the application of the electric vehicle,the prepared film still showed an energy storage density of 1.5 J cm^(-3)and charge-discharge efficiency of 86%,which is 3 times that of BOPP film.This work provides an idea for material designs of high-performance polymer film capacitors.

关 键 词：Epoxy film Amine hardeners Flexible side chain Thermodynamic properties Dielectric properties Energy storage performance 

分 类 号：TM53[电气工程—电器] TB383.2[一般工业技术—材料科学与工程]