Wet Spinning Fabrication of Robust and Uniform Intrinsically Conductive Cellulose Nanofibril/Silk Conductive Fibers as Bifunctional Strain/Humidity Sensor in Potential Smart Dressing  

作　　者：Ruixin Gong Yanjuan Dong Dan Ge Zhouyu Miao Hou‑Yong Yu 

机构地区：[1]Key Laboratory of Intelligent Textile and Flexible Interconnection of Zhejiang Province,Zhejiang Sci-Tech University,Hangzhou 310018,China [2]State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,Donghua University,Shanghai 201620,China

出　　处：《Advanced Fiber Materials》2024年第4期993-1007,共15页先进纤维材料（英文）

基　　金：supported by National Natural Science Foundation of China(52273095);Outstanding Youth Project of Zhejiang Provincial Natural Science Foundation(LR22E030002);the Open Fund of State Key Laboratory of Biobased Fiber Manufacturing Technology(SKL202301);State Key Laboratory for Modification of Chemical Fibers and Polymer Materials(KF2314).

摘　　要：Silk fibroin(SF)with skin-like features and function shows great prospects in wearable electronics and smart dressing.However,the traditional method of loading conductive materials on physical interfaces can easily lead to the detachment of conductive materials,poor mechanical properties,and unstable conductivity,which hinder their practical application.Herein,simple wet spinning was utilized to fabricate multifunctional regenerated silk fibers reinforced with different contents of intrinsically conductive cellulose nanofibril(CNFene).Significant enhancements in fiber homogeneity,thermal stability,conductivity,mechanical strength,and sensing ability were achieved due to more regular orientation of silk fibroin molecules and strong intermolecular interactions with CNFene.The optimized sample(SF_(1))with high sensitivity(100 ms),excellent washing/rubbing resistance,and superb waterproof properties(22 days)can comprehensively monitor human motion and weak signals.Surprisingly,inspired by the different humidity levels around wounds at different stages of healing,SF1 with favorable humidity sensitivity can be developed as a smart dressing for monitoring wound healing.Therefore,this work provides a simple preparation route of smart high-performance fiber for flexible electronic devices,smart dressing,and underwater smart textiles.

关 键 词：Silk fibroin CNFene Mechanical strength Wound monitoring 

分 类 号：TP212[自动化与计算机技术—检测技术与自动化装置]