S/NiFeP/KB复合材料锂硫电池正极的性能  

Preparation and Performance of S/NiFeP/KB Composites Electrocatalyst for Lithium Sulfur Batteries

作　　者：武静[1] 张子怡 韩旭 侯星延 李雪艳 李莎莎 刘雯[1] 李鹏[1] WU Jing;ZHANG Ziyi;HAN Xu;HOU Xingyan;LI Xueyan;LI Shasha;LIU Wen;LI Peng(Taiyuan University of Science and Technology,College of Engineering and Technology,Taiyuan 030024,China)

机构地区：[1]太原科技大学化学工程与技术学院,太原030024

出　　处：《材料研究学报》2024年第11期828-836,共9页Chinese Journal of Materials Research

基　　金：国家自然科学基金(22278251);大学生创新创业训练计划(202210109013)。

摘　　要：将2D纳米片NiFeP生长在Ketjen Black ECP-600JD炭黑(KB)上制备出花球颗粒状NiFeP/KB电催化剂,再将其与纳米硫颗粒按适当比例均匀混合制备出锂硫电池的正极。这种S/NiFeP/KB正极在0.1C下首次放电比容量为1454.5 mAh/g,循环200次后仍有821.1 mAh/g,在2C下300次循环后比容量为639.9 mAh/g,容量保持率达74.7%;使用NiFeP/KB电催化剂能提高电池中多硫化锂的氧化、还原反应速率,从而改善锂、硫反应动力学。Transition metal phosphide has not only metal-like conductive properties but good adsorp-tion and catalytic conversion of polysulfide lithium.In this paper,the NiFeP/KB electrocatalyst grown by 2D nanosheet NiFeP on Ketjen Black ECP-600JD carbon black(KB)was prepared.The S/NiFeP/KB cathode material was obtained by mixing the nano sulfur particles with NiFeP/KB in a proportional and uniform way.Due to the synergistic effect of metal doping and hierarchical structure,the electrode pre-pared using S/NiFeP/KB material had a specific capacity of 1454.5 mAh/g at 0.1C for the first discharge,which remained 821.1 mAh/g after 200 cycles,639.9 mAh/g after 300 cycles at 2C,and the capacity re-tention rate reached 74.7%.Further combined with CV and EIS tests,the NiFeP/KB electrocatalyst can effectively improve the oxidation and reduction reaction rate of lithium polysulfide in the battery,thus pro-moting the reaction kinetics of lithium and sulfur.

关 键 词：复合材料 锂硫电池 双金属磷化物 NiFeP 纳米硫颗粒 电催化剂 

分 类 号：TM911[电气工程—电力电子与电力传动]