Direct photoelectrochemical nitrate synthesis in an acidic electrolyte from N_(2)by a hole coupled oxygen atom transfer process  

作　　者：Zhongyuan Ma Jiaming Miao Kwanghee Kim Gyuyong Jang Youngmoon Choi Seongjae Im Joonhee Kang Kan Zhang Jong Hyeok Park 

机构地区：[1]Department of Chemical and Biomolecular Engineering,Yonsei University,50 Yonsei-ro,Seodaemun-gu,Seoul 120-749,Republic of Korea [2]School of Materials Science and Engineering and School of Chemistry and Chemical Engineering,Nanjing University of Science and Technology,Nanjing 20094,Jiangsu,China [3]Department of Nanoenergy Engineering,Pusan National University,Busan 46241,Republic of Korea

出　　处：《Journal of Energy Chemistry》2024年第12期654-660,共7页能源化学（英文版）

基　　金：supported by the National Natural Science Foundation of China(T2322013);supported by the Ministry of Science and ICT through the National Research Foundation of Korea(2022H1D3A3A01077254,NRF-2019R1A2C3010479)。

摘　　要：Ammonia is an important chemical for pharmaceutical,agriculture,industry,as well as energy production et al.However,the industrial production of ammonia using the Haber-Bosch process is energy-intensive,which stimulates us to explore a cost-effective and low-carbon footprint way for the synthesis of ammonia[1–3].Electrochemical(EC)synthesis of ammonia from an aqueous N_(2)reduction reaction(NRR)has gained significant attention in recent years,while the high dissociation energy of the N≡N bond(941 kJ/mol),as well as higher over-potential than hydrogen evolution reaction(HER),cause a lower efficiency[4].

关 键 词：Nitrogen oxidation Tungsten oxide Facet engineering PHOTOELECTROCHEMICAL Oxygen atom transfer 

分 类 号：TQ113.2[化学工程—无机化工] O643.36[理学—物理化学]