无负极锂金属电池在局部高浓度电解液中的产气研究  

Gas Generation in Anode-Free Li-Metal Batteries with Localized High-Concentration Electrolytes

作　　者：郭姿珠[1] 张睿 孙旦[1] 王海燕[1] 黄小兵 唐有根[1] Guo Zizhu;Zhang Rui;Sun Dana;Wang Haiyana;Huang Xiaobing;Tang Yougen(College of Chemistry and Chemical Engineering,Central South University,Changsha 410083,China;School of Chemistry and Materials Engineering,Hunan University of Arts and Science,Changde 415000,China)

机构地区：[1]中南大学化学化工学院,长沙410083 [2]湖南文理学院化学与材料工程学院,常德415000

出　　处：《化学学报》2024年第9期919-924,共6页Acta Chimica Sinica

基　　金：国家自然科学基金(No.22272205);国家资助博士后研究人员计划(No.GZC20233152);湖南省普通高等学校科技创新团队支持项目资助~~

摘　　要：引入局部高浓电解液(LHCE)是提升金属锂负极循环稳定性的重要方法之一.虽然该类电解液在提高无负极锂金属电池(AF-LMB)循环寿命方面已有报道,但是较少有研究关注电解液的分解反应和产气情况.本工作组装了软包全电池Cu||NCM712,研究了LHCE电解液浓度、工作温度以及充电截止电压对AF-LMB体系产气情况的影响.结合气相色谱、Raman光谱以及电化学测试,发现锂盐浓度是影响循环寿命和产气量的显著因子,提高锂盐浓度可以减少LHCE中自由溶剂分子的数量,抑制电解液的氧化分解和电池产气.The introduction of localized high-concentration electrolyte(LHCE),which inherits the advanced properties of concentrated electrolytes and exhibits lower viscosity and cost,is one of the important methods to improve the cycling stability of lithium metal anode.Although the similar strategy also has been proposed to extend the durable life of anode-free lithium metal batteries(AF-LMBs),few studies have focused on the electrolyte decomposition reaction and gas production.In this work,a typical LHCE system consisting of lithium bis(fluorosulfonyl)imide(LiFSI)salt,1,2-dimethoxyethane(DME)solvent and tetrafluoroethyl tetrafluoropropyl ether(HFE)diluter were chosen,and Cu||NCM712 pouch cells were assembled to investigate the effects of LHCE concentration(0.7,1.2,1.7 and 2.3 mol/L),working temperature(25 and 45℃)and charging cutoff voltage(3.8 and 4.3 V)on the gas production of AF-LMB systems.Combined with gas chromatography,Raman spectroscopy and electrochemical tests,it is found that the concentration of lithium salt is a significant factor affecting the cycle life and gas production volume.The solvation structure gradually evolves and the number of free solvent molecules in LHCE reduces as the concentration of lithium salt increases,inhibiting the oxidation decomposition of electrolyte and gas production of battery.Moreover,the electrolyte decomposition is also dependent with the variety of cathode material.In contrast with lithium iron phosphate(LiFePO4)cathode,NCM712 cathode results in faster capacity decay of the full-cell and higher gas volume,which might be ascribed to the transition metal elements with the catalytic effect.Meanwhile,scanning electron microscope images indicate uniform and dense lithium deposition on the Cu foil,and X-ray photoelectron spectroscopy tests also reveal that more inorganic solid electrolyte interface(SEI)components are formed on the surface of lithium metal,which serves as the excellent protective layer and is beneficial to suppressing the side reaction.This work is expected to pr

关 键 词：无负极锂金属电池 局部高浓电解液 产气分析 溶剂化结构 

分 类 号：TM912[电气工程—电力电子与电力传动] O646.1[理学—物理化学]