Structurally altered size,composition,shape and interfacedependent optical properties of quantized nanomaterials  

作　　者：Neng Qin Hui Han Guijian Guan Ming-Yong Han 

机构地区：[1]Institute of Molecular Plus,Tianjin University,Tianjin 300072,China

出　　处：《Nano Research》2024年第12期10543-10569,共27页纳米研究（英文版）

基　　金：supported by the National High Technology Research and Development Program of China(No.2021YFF1200200);the Peiyang Talents Project of Tianjin University.

摘　　要：The impact of the size effect on the color and photoluminescence(PL)of quantum dots(QDs)has sparked a revolutionary field of research,culminating in the prestigious Nobel Prize in 2023.Prior to their widespread popularization and large-scale commercialization,it is of paramount importance to effectively manipulate and optimize their optical properties.In this review,we place specific emphasis on the striking correlation between the optical characteristics of QDs and their size,structure,composition,and interface environment.We commence by tracing the evolution of quantum dot technology and subsequently categorizing QDs while outlining their typical synthesis methods.This is followed by a deep dive into the pivotal roles of size,composition,structure,and interfacial ligands in fine-tuning,optimizing,and enhancing the optical properties of QDs.Additionally,we illustrate the luminescence enhancement and charge transfer phenomena stemming from the heterojunction between semiconductor QDs and metal nanomaterials,which contribute to improved performance.Lastly,we introduce the burgeoning field of chiral QDs and their innovative applications.Armed with this knowledge,QDs can be readily tailored to exhibit adjustable luminous characteristics across the entire spectrum,boasting high luminous efficiency through multifaceted regulation.These advancements render QDs even more enticing and promising for a wide array of applications.

关 键 词：NANOCLUSTERS quantum dots size effect composition effect optical property chiral characteristics 

分 类 号：TB383[一般工业技术—材料科学与工程]