Morphological complexity and azimuthal disorder of evolving pore space in low-maturity oil shale during in-situ thermal upgrading and impacts on permeability  

作　　者：Jun Liu Yan-Bin Yao Derek Elsworth 

机构地区：[1]Key Laboratory of Deep Underground Science and Engineering(Ministry of Education),Institute of New Energy and Low-Carbon Technology,Sichuan University,Chengdu,610065,Sichuan,Chin [2]School of Energy Resource,China University of Geosciences Beijing,Beijing,100083,China [3]Department of Energy and Mineral Engineering,Pennsylvania State University,Park,PA,16802,USA

出　　处：《Petroleum Science》2024年第5期3350-3362,共13页石油科学（英文版）

基　　金：financially supported by the National Key Research and Development Program of China (Grant No. 2022YFE0129800);the National Natural Science Foundation of China (Grant No. 42202204);support from the G. Albert Shoemaker endowment。

摘　　要：In-situ thermal upgrading is used to tune the pore system in low-maturity oil shales. We introduce fractal dimension(D), form factor(ff) and stochastic entropy(H) to quantify the heating-induced evolution of pore morphological complexity and azimuthal disorder and develop a model to estimate the impact on seepage capacity via permeability. Experiments are conducted under recreated in-situ temperatures and consider anisotropic properties—both parallel and perpendicular to bedding. Results indicate that azimuthal distribution of pores in the bedding-parallel direction are dispersed, while those in the bedding-perpendicular direction are concentrated. D values indicate that higher temperatures reduce the uniformity of the pore size distribution(PSD) in the bedding-parallel direction but narrow the PSD in the bedding-perpendicular direction. The greater ff(> 0.7) values in the bedding-parallel direction account for a large proportion, while the dominated in the bedding-perpendicular direction locates within 0.2-0.7, for all temperatures. The H value of the bedding-parallel sample remains stable at ~0.925 during heating, but gradually increases from 0.808 at 25℃ to 0.879 at 500℃ for the beddingperpendicular sample. Congruent with a mechanistic model, the permeability at 500℃ is elevated~1.83 times(bedding-parallel) and ~6.08 times(bedding-perpendicular) relative to that at 25℃—confirming the effectiveness of thermal treatment in potentially enhancing production from low-maturity oil shales.

关 键 词：Low-maturity oil shale Fractal dimension Form factor Pore structure Fluid seepage capacity 

分 类 号：TE311[石油与天然气工程—油气田开发工程]