MOFs阻燃高分子材料应用研究进展  

Research progress in application of MOFs flame retardant polymer materials

作　　者：单春燕 秦舒浩 胡智[1,2] 刘琪 庞会霞[1,2] 龙丽娟 向宇姝 SHAN Chunyan;QIN Shuhao;HU Zhi;LIU Qi;PANG Huixia;LONG Lijuan;XIANG Yushu(Guizhou Material Industrial Technology Institute,Guiyang 550014,China;The National Composite Modified Polymer Material Engineering Technology Research Center,Guiyang 550014,China;School of Materials and Architectural Engineering,Guizhou Normal University,Guiyang 550025,China)

机构地区：[1]贵州省材料产业技术研究院,贵阳550014 [2]国家复合改性聚合物材料工程技术研究中心,贵阳550014 [3]贵州师范大学材料与建筑工程学院,贵阳550025

出　　处：《工程塑料应用》2024年第12期171-176,共6页Engineering Plastics Application

基　　金：国家自然科学基金项目(22065008);贵州省科技支撑计划项目(黔科合支撑[2023]一般312);贵州省中央引导地方科技发展资金项目(黔科合中引地[2023]035);贵州省科研机构创新能力建设专项资金项目(黔科合服企[2023]001)。

摘　　要：金属有机骨架化合物(MOFs)是一类独特的无机-有机杂化结构化合物,它是由中心金属离子(簇)与有机配体形成的多孔类化合物,在吸附、药物运输以及阻燃领域有广泛的应用。简要阐述了MOFs的基本结构、分类,综述了MOFs单独作为阻燃剂以及与其他化合物协效阻燃高分子材料的最新研究进展,分析了不同MOFs阻燃剂在高分子复合材料中的阻燃效果及其阻燃机理,总结了MOFs系阻燃剂的阻燃机理。最后,展望了MOFs材料在高分子材料中的阻燃应用前景。Metal-organic frameworks(MOFs)are a kind of unique inorganic-organic hybrid structural compounds,which are porous compounds formed by central metal ions(clusters)and organic ligands,and have a wide range of applications in adsorption,drug transport and flame retardant fields.The basic structure and classification of MOFs were briefly described,the latest research progress of MOFs as a single flame retardant in flame retardant polymer materials and in collaboration with other compounds for synergistic flame retardant polymer materials was reviewed,the flame retardant effect and flame retardant mechanism of different MOFs flame retardants in polymer composites were analyzed,and the flame retardant mechanism of MOFs flame retardants was summarized.Finally,the flame retardancy application of MOFs in polymer materials was prospected.

关 键 词：金属有机骨架化合物(MOFs) 阻燃剂 阻燃机理 协效阻燃 无机-有机杂化 

分 类 号：TQ050.425[化学工程]