SiO_(2)/Al_(2)O_(3)对吉州窑黑釉“梨皮纹”影响机制研究  

Study on the Influence Mechanism of SiO_(2)/Al_(2)O_(3)on the“Pear Peel Pattern”of Black Glaze in Jizhou Kiln

作　　者：杨晶 周瑜[3] 刘溧 徐和良 赵田贵 包启富 YANG Jing;ZHOU Yu;LIU Li;XU He-liang;ZHAO Tian-gui;BAO Qi-fu(Jingdezhen Ceramic University,Jingdezhen 333403,China;Jiangsu Baifu Technology Co.,Ltd.,Wuxi 214200,China;Jingdezhen University,Jingdezhen 333032,China)

机构地区：[1]景德镇陶瓷大学,景德镇333403 [2]江苏拜富科技股份有限公司,无锡214200 [3]景德镇学院,景德镇333032

出　　处：《中国陶瓷》2024年第12期97-103,共7页China Ceramics

摘　　要：“梨皮纹”是吉州窑黑釉的典型特征之一。以吉州窑黑釉为研究对象,采用高岭土、狼萁草灰和滑石等为主要原料仿制吉州窑“梨皮纹”黑釉。实验通过探究SiO_(2)/Al_(2)O_(3)对吉州窑黑釉显微结构及性能的影响,揭示了独特“梨皮纹”釉面的形成机制。结果表明:当SiO_(2)含量在4.0~5.0 mol,Al_(2)O_(3)含量在0.55~0.60 mol(SiO_(2)/Al_(2)O_(3):6.6~9.1),釉面形成类似吉州窑黑釉瓷独特的“梨皮纹”褶皱纹理。这主要是由于釉层在高温烧制与冷却过程中,高SiO_(2)与Al_(2)O_(3)含量增大釉熔体黏度。同时,釉层氧化铁分解产生分相,生成少量赤铁矿和钙长石,以及残留石英晶体,从而使釉面形成了“梨皮纹”特征的褶皱状黑色调纹理。“Pear peel pattern”is one of the typical characteristics of the black glaze of Jizhou Kiln.This paper focuses on the black glaze of Jizhou Kiln,using kaolin,pteris multifida ash and talc as the main raw materials to replicate the“pear peel pattern”black glaze of Jizhou Kiln.By exploring the effects of SiO_(2)/Al_(2)O_(3)on the microstructure and properties of the black glaze in Jizhou Kiln,the formation mechanism of the unique“pear peel pattern”glaze was revealed.The results show that when the content of SiO_(2)is in the range of 4.0~5.0 mol and the Al_(2)O_(3)content is in the range of 0.55~0.60 mol(SiO_(2)/Al_(2)O_(3):6.6~9.1),the glaze surface exhibits a unique“pear peel pattern”fold texture similar to that of Jizhou Kiln black glaze porcelain.This is mainly due to the increased viscosity of the glaze melt caused by high SiO_(2)and Al_(2)O_(3)content during the high-temperature firing and cooling process.At the same time,the decomposition of iron oxide in the glaze layer produces phase separation,generating a small amount of hematite and calcium feldspar,as well as residual quartz crystals,thus forming a wrinkled black texture of“pear peel pattern”characteristics on the glaze.

关 键 词：吉州窑 黑釉 梨皮纹 SiO_(2)/Al_(2)O_(3) 形成机理 

分 类 号：TQ174.43[化学工程—陶瓷工业]