Recent progress in constructing fluorinated solid-electrolyte interphases for stable lithium metal anodes  

作　　者：Di Zhang Pengfei Lv Wei Qin Xin He Yuanhua He 

机构地区：[1]Civil Aircraft Fire Science and Safety Engineering Key Laboratory of Sichuan Province,College of Civil Aviation Safety Engineering,Civil Aviation Flight University of China,Guanghan 618307,China [2]School of Chemical Engineering,Sichuan University,Chengdu 610065,China

出　　处：《International Journal of Minerals,Metallurgy and Materials》2025年第2期270-291,共22页矿物冶金与材料学报（英文版）

基　　金：support from the National Natural Science Foundation of China(No.U2333210);the Sichuan Science and Technology Program,China(No.21SYSX0011)。

摘　　要：Lithium metal batteries(LMBs)are emerging as a promising energy storage solution owing to their high energy density and specific capacity.However,the non-uniform plating of lithium and the potential rupture of the solid-electrolyte interphase(SEI)during extended cycling use may result in dendrite growth,which can penetrate the separator and pose significant short-circuit risks.Forming a stable SEI is essential for the long-term operation of the batteries.Fluorine-rich SEI has garnered significant attention for its ability to effectively passivate electrodes,regulate lithium deposition,and inhibit electrolyte corrosion.Understanding the structural components and preparation methods of existing fluorinated SEI is crucial for optimizing lithium metal anode performance.This paper reviews the research on optimizing LiF passivation interfaces to protect lithium metal anodes.It focuses on four types of compositions in fluorinated SEI that work synergistically to enhance SEI performance.For instance,combining compounds with LiF can further enhance the mechanical strength and ionic conductivity of the SEI.Integrating metals with LiF significantly improves electrochemical performance at the SEI/anode interface,with a necessary focus on reducing electron tunneling risks.Additionally,incorporating polymers with LiF offers balanced improvements in interfacial toughness and ionic conductivity,though maintaining structural stability over long cycles remains a critical area for future research.Although alloys combined with LiF increase surface energy and lithium affinity,challenges such as dendrite growth and volume expansion persist.In summary,this paper emphasizes the crucial role of interfacial structures in LMBs and offers comprehensive guidance for future design and development efforts in battery technology.

关 键 词：LIF lithium metal anodes solid-electrolyte interphase interface cycling stability 

分 类 号：TM912[电气工程—电力电子与电力传动] O646[理学—物理化学]