微波辐照改性聚酯短纤维/天然橡胶复合材料的界面结构与性能研究  

Study on Interfacial Structures and Properties of Microwave Irradiated Modified Polyester Short Fiber/NR Composites

作　　者：谭浩东 罗勇欢[2] 童鑫 刘书银 刘鸿鑫 刘安宇 郭森 李国洪 刘清亭[1,2] TAN Haodong;LUO Yonghuan;TONG Xin;LIU Shuyin;LIU hongxin;LIU Anyu;GUO Sen;LI Guohong;LIU Qingting(Hubei University of Technology,Wuhan 430068,China;Zhuzhou Times New Material Technology Co.,Ltd,Zhuzhou 412007,China;Shiyan Hutchinson-DFEDC Automotive Seals Co.,Ltd,Shiyan 442000,China)

机构地区：[1]湖北工业大学绿色轻工材料湖北省重点实验室,湖北武汉430068 [2]株洲时代新材料科技股份有限公司,湖南株洲412007 [3]十堰东森汽车密封件有限公司,湖北十堰442000

出　　处：《橡胶工业》2025年第1期3-9,共7页China Rubber Industry

基　　金：绿色轻工材料湖北省重点实验室开放基金项目(202207B02)。

摘　　要：采用微波辐照工艺和硅烷偶联剂KH550对聚酯[聚对苯二甲酸乙二醇酯(PET)]短纤维进行表面改性,制备改性PET(MPET)短纤维/天然橡胶(NR)复合材料,并对其结构和性能进行研究。结果表明:在微波活化作用下,硅烷偶联剂KH550附着于PET短纤维表面,有利于改善PET短纤维与橡胶基体之间的界面粘合性能;与PET/NR复合材料相比,MPET/NR复合材料的交联密度、定伸应力和撕裂强度增大,拉断伸长率减小,动态力学性能提高。Polyester[polyethylene terephthalate(PET)]short fibers were surface modified by microwave irradiation process and silane coupling agent KH550,modified PET(MPET)short fiber/natural rubber(NR)composites were prepared and their interfacial structures and properties were studied.The results showed that under microwave activation,silane coupling agent KH550 was attached to the surface of PET short fiber,which was beneficial for improving the interfacial adhesion performance between PET short fiber and rubber matrix.Compared with PET short fiber/NR composite,the crosslink density,modulus and tear strength of MPET short fiber/NR composite increased,the elongation at break decreased,and the dynamic mechanical properties were improved.

关 键 词：聚酯短纤维 天然橡胶 微波辐照 硅烷偶联剂 改性 界面结构 

分 类 号：TQ330.389[化学工程—橡胶工业] TQ332.6