超临界反应及超临界流体参与的反应研究与应用进展  

Progress in supercritical reactions and supercritical fluid participated reactions and their applications

作　　者：王永涛 毛建拥 胡柏剡 王欣雨 刘佳欣 姚加[1,2] 李浩然[1,2] WANG Yongtao;MAO Jianyong;HU Baishan;WANG Xinyu;LIU Jiaxin;YAO Jia;LI Haoran(Department of Chemistry,Zhejiang University,Hangzhou 310058,Zhejiang,China;Center of Chemistry for Frontier Technologies,Zhejiang University,Hangzhou 310058,Zhejiang,China;Shandong NHU Vitamin Ltd.,Weifang 261108,Shandong,China;Zhejiang NHU Company Ltd.,Shaoxing 312500,Zhejiang,China)

机构地区：[1]浙江大学化学系,浙江杭州310058 [2]浙江大学化学前瞻技术研究中心,浙江杭州310058 [3]山东新和成维生素有限公司,山东潍坊261108 [4]浙江新和成股份有限公司,浙江绍兴312500

出　　处：《化工学报》2024年第11期3973-3986,共14页CIESC Journal

基　　金：国家重点研发计划项目(2022YFA1503200);国家自然科学基金项目(22303079);浙江省自然科学基金项目(LQ22B030011)。

摘　　要：物质在超临界条件下有独特的性质与反应活性,常被用作为超临界反应介质,但作为反应物被实际应用于化工反应的例子并不多见。聚焦于至少一种反应物处于超临界条件的反应,总结其在一些具有化工实践价值反应中的应用,特别关注所有反应物均处于超临界状态时超临界反应的基础研究及工业应用,并展望了该技术未来的研究方向与发展前景。Substances have unique properties and reactivity under supercritical reactions and are often used as supercritical reaction media,but there are few examples of them being actually used as reactants in chemical reactions.This paper focuses on reactions where at least one reactant is a supercritical fluid,summarizing their applications in some industrially valuable reactions.This review particularly emphasizes the fundamental research and industrial applications of supercritical reactions where all reactants are in a supercritical state,while also looking ahead to future research directions and prospects for this technology.

关 键 词：超临界流体 超临界反应 绿色化工技术 

分 类 号：TQ02[化学工程]