一种[60]富勒烯吡咯烷并六氢苯并恶唑嗪衍生物的合成研究  

The synthesis of novel[60]fulleropyrrolidine-fused hexahydrobenzoxazocine derivatives

作　　者：唐莉红 付华宇 苏馨 白淑婉 李法宝 TANG Lihong;FU Huayu;SU Xin;BAI Shuwan;LI Fabao(College of Chemistry and Chemical Engineering,Hubei University,Wuhan 430062,China)

机构地区：[1]湖北大学化学化工学院,湖北武汉430062

出　　处：《湖北大学学报（自然科学版）》2025年第1期136-145,共10页Journal of Hubei University：Natural Science

基　　金：国家自然科学基金(22271083);湖北省大学生创新创业训练计划(S202310512020)资助。

摘　　要：近年来,含氮杂环[60]富勒烯衍生物已被广泛应用于钙钛矿太阳能电池的研究中,它们作为界面修饰材料能够有效提高太阳能电池的光电转换效率。因此,继续开发制备新型[60]富勒烯含氮杂环衍生物的反应十分必要。本研究通过Pb(OAc)2促进的[60]富勒烯与2-(3-溴丙氧基)苯甲醛和芳甲胺的简单一步反应,合成了一系列少有报道的含氮杂环[60]富勒烯吡咯烷并六氢苯并恶唑嗪衍生物。该合成方法具有操作简单,原料廉价易得,产物结构新颖等优点,有助于富勒烯光伏材料在钙钛矿太阳能电池领域的进一步应用。In recent years,[60]fullerene derivatives containing nitrogen heterocyclic moieties have been extensively applied in the field of perovskite solar cells(PSCs).As interfacial modification materials,they can effectively enhance power conversion efficiency of solar cells.Therefore,it is necessary to continue to develop new type of fullerene reactions for the synthesis of novel nitrogen-containing heterocyclic[60]fullerene derivatives.In this paper,a simple one-step reaction of[60]fullerene with 2-(3-bromopropoxy)benzaldehyde and arylmethanamines promoted by Pb(OAc)2 was studied and a series of unreported nitrogen-containing heterocyclic[60]fulleropyrrolidine-fused hexahydrobenzoxazocine derivatives were synthesized.This reaction has the advantages of simple operation,cheap and easily available raw materials,and novel product structure,which is conducive to further application of fullerene photovoltaic materials in the field of PSCs.

关 键 词：富勒烯 醋酸铅 芳甲胺 富勒烯吡咯烷并六氢苯并恶唑嗪 

分 类 号：O626[理学—有机化学]