棕榈酰化三聚氰胺的合成与性质  

Preparation and Properties of Melamine Derivatives Modified with Palmitoyl Chloride

作　　者：张继尧 曹立久 熊小燕 胡悦 李娜 陈玉放[1,2,3,4,5,6] 靳焘 ZHANG Jiyao;CAO Lijiu;XIONG Xiaoyan;HU Yue;LI Na;CHEN Yufang;JIN Tao(Guangzhou Institute of Chemistry,Chinese Academy of Sciences,Guangzhou 510650,China;University of Chinese Academy of Sciences,Beijing 100049,China;CAS Testing Technical Services(Guangzhou)Co.Ltd.,Guangzhou 510650,China;CAS Engineering Laboratory for Special Fine Chemicals,Guangzhou 510650,China;CASH GCC Shaoguan Research Institute of Advanced Materials,Shaoguan 512400,China;CASH GCC Fine Chemicals Incubator(Nanxiong)Co.,Ltd,Nanxiong 512400,China)

机构地区：[1]中国科学院广州化学研究所,广东广州510650 [2]中国科学院大学,北京101408 [3]中科检测技术服务(广州)股份有限公司,广东广州510650 [4]中国科学院新型特种精细化学品工程实验室,广东广州510650 [5]国科广化韶关新材料研究院,广东韶关512400 [6]国科广化精细化工孵化器(南雄)有限公司,广东南雄512400

出　　处：《广州化学》2024年第6期60-65,I0004,共7页Guangzhou Chemistry

摘　　要：以十六碳酰氯(棕榈酰氯)为酰化剂与三聚氰胺进行反应,制备了十六碳酰化三聚氰胺(PM),并优化了反应条件;探究了棕榈酰氯、草酰氯、磺酰氯及丙烯酰氯四种酰化剂,制备得到相应的酰化三聚氰胺,对比了反应条件和产物性能;最后对比了密胺树脂(MF)以及棕榈酰化密胺树脂(PMF)的性能。用FT-IR、^(1)H-NMR以及SEM表征分析了PM的结构,用TGA研究了PM的热稳定性。结果表明,该合成方法以及纯化方法产率高(90%),产物热分解温度高(367.4℃),PM粉末具有疏水性,其水接触角最高达143°。PMF树脂比MF树脂具有更高的固含量(59.8%)和更高的粘度(150.6 m Pa·s),对MF树脂后续的研究应用有着重要意义。The reaction between melamine and hexadecanoyl chloride(palmitoyl chloride)as an acylating agent resulted in the production of hexadecanoylated melamine(PM)after optimizing the reaction conditions.Four acylating agents,namely palmitoyl chloride,oxaloyl chloride,sulfonyl chloride,and acryloyl chloride,were used to obtain the corresponding acylated melamine.The reaction conditions and product properties were compared,followed by a comparison of the properties of the dermatomimetic resins(MFs)and palmitoylated dermatomimetic resins(PMFs).Finally,a comparison was made between the properties of MF and PMF.The PM structure underwent analysis through FT-IR,^(1)H-NMR,and SEM characterization.Additionally,the thermal stability of PM was studied using TGA.The results indicate that the synthesis and purification method produced a high yield(90%)and a high thermal decomposition temperature(367.4℃).Furthermore,the PM powder exhibited hydrophobicity with a water contact angle of up to 143°.The PMF resin has a higher solids content(59.8%)and viscosity(150.6 mPa·s)compared to MF resin,which is significant for future research and application of MF resin.

关 键 词：三聚氰胺 棕榈酰化三聚氰胺 酰胺化反应 自疏水性 棕榈酰化密胺树脂 

分 类 号：TB34[一般工业技术—材料科学与工程]