Review of Antifouling Finishing of Textiles:Theme,Evolution and Fabrication Methods  

纺织品防污整理综述:主题、演进与方法

作　　者：DING Fengmei GUO Yali WANG Qingmiao WANG Xuehui WANG Ping XING Zhiqi CHEN Luyi 丁凤美;郭亚丽;王庆淼;王雪慧;王平;邢志奇;陈璐怡(东华大学化学与化工学院,上海201620;东华大学国家染整工程技术研究中心,上海201620;雅戈尔集团股份有限公司,浙江宁波315153;上海市国资国企改革发展研究中心,上海200233)

机构地区：[1]College of Chemistry and Chemical Engineering,Donghua University,Shanghai 201620,China [2]National Engineering Research Center for Dyeing and Finishing of Textiles,Donghua University,Shanghai 201620,China [3]Youngor Group Co.,Ltd.,Ningbo 315153,China [4]Shanghai Research Center for Reform and Development of State-Owned Assets and State-Owned Enterprises,Shanghai 200233,China

出　　处：《Journal of Donghua University(English Edition)》2024年第6期616-629,共14页东华大学学报（英文版）

基　　金：Fundamental Research Funds for the Central Universities,China(No.2232021G-03);National Natural Science Foundation of China(Nos.72074132 and 71704165)。

摘　　要：Antifouling textiles have been a hot research field in the last ten years.But lately,the European Union(EU)is expected to ban the production of C6 fluorinated water repellent,oil repellent and antifouling agents from 2025,achieving complete fluoride-free antifouling measures.In the context of the current policy regulations on fluorine-free treatment in the waterproof,oil repellent and antifouling finishing field,this paper conducts a literature survey and comprehensive understanding of the current research status and trend in fluorine-free antifouling finishing.CiteSpace and Carrot2 are used to conduct a literature review of the latest papers in two databases,Web of Science(WoS)and China National Knowledge Infrastructure(CNKI).Firstly,the theoretical evolution and technical characteristics of textiles antifouling finishing technology are systematically discussed,and the technological differences of antifouling finishing textiles for different demands are compared.Secondly,the three main stages of the development of textile antifouling finishing technology and its corresponding finishing methods are summarized.Finally,three paths for the future development of fluorine-free antifouling finishing are prospected:construction of low surface energy,construction of uniform rough surface and low surface energy,and construction of multistage rough surface with low surface energy.To facilitate the transition of the industrial sector to fluorine-free,regulatory restrictions could be strengthened by enhancing the sampling inspection of apparel fabrics,detecting fluorine in wastewater discharges and restricting the production of fluorine-containing finishing agents by manufacturers.防污纺织品是近十年来研究的热点。欧洲计划从2025年起禁止生产C6含氟三防(防水、防油、防污)整理剂,实现完全无氟防污。该综述结合三防领域现行无氟处理政策规定,进行文献调查、分析和总结,了解无氟防污整理的研究现状和趋势。采用CiteSpace和Carrot2对Web of Science和CNKI两个数据库中的最新论文进行文献综述研究。首先,系统讨论了纺织品防污整理的理论演进和技术特点,并比较了不同需求的防污整理纺织品的技术差异。其次,总结了纺织品防污整理发展的三个主要阶段及其相应的整理方法。最后,展望了无氟防污整理未来发展的三条路径:低表面能结构、均匀粗糙低表面能结构、多级粗糙低表面能结构。为促进工业领域的生产和使用向无氟转型,应加强监管限制,加强对服装面料的抽样检查,检测废水排放中的氟,并限制制造商生产含氟整理剂。

关 键 词：antifouling finishing fluorine-free HYDROPHOBICITY OLEOPHOBICITY surface roughness 

分 类 号：TS1[轻工技术与工程—纺织科学与工程]