Multi-level hollow sphere rich in heterojunctions with dual function:Efficient microwave absorption and antiseptic  

作　　者：Liyuan Yu Di Lan Zhiqiang Guo Ailing Feng Guanglei Wu Zirui Jia Xing Feng Pengfei Yin 

机构地区：[1]College of Science,Sichuan Agricultural University,Ya’an 625014,China [2]School of Materials Science and Engineering,Hubei University of Automotive Technology,Shiyan 442002,China [3]Institute of Materials for Energy and Environment,State Key Laboratory of Bio-fibers and Eco-textiles,College of Materials Science and Engineering,Qingdao University,Qingdao 266071,China [4]Institute of Physics&Optoelectronics Technology,Baoji University of Arts and Sciences,Baoji 721016,China

出　　处：《Journal of Materials Science & Technology》2024年第22期155-165,共11页材料科学技术（英文版）

基　　金：financially supported by the National Natural Sci-ence Foundation of China(Nos.52377026 and 52301192);the Tais-han Scholars and Young Experts Program of Shandong Province(No.tsqn202103057);the Qingchuang Talents Induction Program of Shandong Higher Education Institution(Research and Inno-vation Team of Structural-Functional Polymer Composites);the Special Financial of Shandong Province(Structural Design of High-efficiency Electromagnetic Wave-absorbing Composite Mate-rials and the Construction of Shandong Provincial Talent Teams).

摘　　要：Effective electromagnetic wave absorption is now possible thanks to the design of the dielectric-magnetic double loss mechanism and the rich heterogeneous structure.In this study,hollow carbon spheres with rich heterostructures were synthesized using an easy and effective in situ growing approach.In addition to improving impedance matching,the hollow structure also reduces material density and weight.By modifying the load,this system can alter the dielectric characteristics of MXene,which in turn affects the sample’s ability to absorb electromagnetic waves.MXene and the carbon material create a thick conductive network during the whole electromagnetic wave absorption process,creating the ideal environment for conduction loss.The sample’s ability to attenuate electromagnetic waves is further improved by the interfacial polarization that the rich heterogeneous structure can produce.Co-magnetic nanoparticle nanoparticles are the main source of magnetic loss.The MXene@Co/C-100–800(MCC-100–800)exhibits excellent electromagnetic wave absorption performance under the synergy of multiple loss mechanisms,with the maximum effective absorption bandwidth(EAB_(max))reaching 7.20 GHz and the minimum reflection loss(RL_(min))being–53.99 dB at 2.10 mm.Finally,this work is guided by the coating engineering of MXene and provides new ideas for the rational design of heterostructures of nanomaterials.

关 键 词：HETEROSTRUCTURE Dielectric-magnetic double loss MXene Hollow carbon sphere Electromagnetic wave absorption 

分 类 号：TB383.1[一般工业技术—材料科学与工程]