5,11,17,23-四叔丁基-25,26,27,28-四[3-(甲氧基羰基)苄氧基]杯[4]芳烃包合性能的研究  

Studies on the Inclusion Property of 5,11,17,23-Tetra-tert-butyl-25,26, 27,28-tetrakis[3-(methoxycarbonyl)benzyloxy]calixarene

作　　者：周稚仙[1] 石雅琳[1] 杜晨霞[1] 邢彦军[1] 吴养洁[1] 

机构地区：[1]郑州大学化学系,郑州450052

出　　处：《高等学校化学学报》2002年第12期2281-2283,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金 (批准号 :2 9872 0 34)资助

摘　　要：The synthesis of a novel host blocked in the cone conformation and bearing m-methoxycarbonylbenzyl groups at the lower rim is described. X-ray crystal structure analysis revealed that action of one molecule of compound upon one molecule of CH 3CN or one molecule of CH 3NO 2, forms an intramolecular inclusion complex, respectively, by CH 3-π interactions. The complex of L with tetrabutyl ammonium bromide(TBAB), L·TBAB, was obtained. The results of DTA-TG and XRD analysis of L·TBAB can also be considered as an intramolecular inclusion complex.The synthesis of a novel host blocked in the cone conformation and bearing m-methoxycarbonylbenzyl groups at the lower rim is described. X-ray crystal structure analysis revealed that action of one molecule of compound upon one molecule of CH 3CN or one molecule of CH 3NO 2, forms an intramolecular inclusion complex, respectively, by CH 3-π interactions. The complex of L with tetrabutyl ammonium bromide(TBAB), L·TBAB, was obtained. The results of DTA-TG and XRD analysis of L·TBAB can also be considered as an intramolecular inclusion complex.

关 键 词：包合性能 5 11 17 23-四叔丁基-25 26 27 芳烃 超分子 晶体结构 季铵盐 包合物 

分 类 号：O641.3[理学—物理化学]