C_(60)(Fullerene)及其卤化衍生物在阴离子聚合中的研究  

Research on C_(60)(Fullerene) and its Chloride in Anionic Polymerization

作　　者：柳庆春[1] 陈滇宝[1] 史制强[1] 华静[1] 刘青[1] 

机构地区：[1]青岛化工学院高分子科学与工程学院,青岛266042

出　　处：《高分子通报》2002年第6期33-40,50,共9页Polymer Bulletin

基　　金：国家自然科学基金资助课题 (2 0 0 740 1 8)

摘　　要：综述了近年来C60 及其卤化衍生物在阴离子聚合中的研究进展。在阴离子聚合中 ,C60 可以直接参与反应而进入主链 ,形成超枝化结构 ;C60 可作为阴离子聚合的偶联剂 ,形成星形和线形结构 ;C60 阴离子可以引发阴离子聚合。介绍了偶联产物结构控制的方法 ,以及偶联产物的稳定性。氯化富勒烯也可以作为阴离子聚合的偶联剂 ,生成星形结构聚合物。The advanced development of C 60 and its chloride in anionic polymerization has been reviewed briefly.C 60 can join up with the main chain in the anionic polymerization reaction,resulting in hyperbranched structure;C 60 can link carbanions “living” polymer chain to form starlike or linear architecture;and carbanions on C 60 ,the core of the starlike polymerization,may initiate anionic polymerization.The methods controlling the structures of the products and the stability of star polymers are also discussed.Fullerenes chloride can also be used as coupling reagent in the anionic polymerization reaction to form starlike architecture polymer

关 键 词：C60 卤化衍生物 富勒烯 氯化富勒烯 富勒烯化高分子 阴离子聚合 碳60 偶联剂 

分 类 号：O631.5[理学—高分子化学] O635.[理学—化学]