聚(β-氯乙基缩水甘油醚)键联的'非汉字符号'-Cp_2TiCl_2络合物的合成及其对黄樟油素异构化的催化作用  

SYNTHESIS AND CATALYTIC PROPERTY OF POLY(β-CHLOROETHYL GLYCIDYD-LINKED '非汉字符号'Cp_2TiCl_2

作　　者：刘以寅[1] 荣建辉 玄镇爱[1] 王者福[1] 陈寿山[1] 

机构地区：[1]南开大学元素有机化学研究所,天津300071

出　　处：《Chinese Journal of Catalysis》1992年第1期78-82,共5页催化学报（英文）

基　　金：国家自然科学基金

摘　　要：我们曾报道了聚环氧氯丙烷键联的高分子钛络合物的合成及其催化活性,本文以聚(β-氯乙基缩水甘油醚)为载体,“一锅法”合成了几种高分子钛络合物:With poly(β-chloroethyl glycidyl) as carrier, some new poly(β-chlo-roethyl glycidyl ether)-linked -Cp2TiCl2 complexes were synthesized by 'one pot' method. These products were analyzed and identified. The isomerization of safrole catalyzed by -Cp2TiCl2 was studied. It was proved by ESR that the titano-hydrogen derivatives of polymer-metallic complexes are mainly present in an unpolymeric form.

关 键 词：钛络合催化剂 黄樟油素 异构化 

分 类 号：TQ426.92[化学工程]