面向工业烟道气CO_(2)捕获的基于廉价配体金属有机骨架材料的研究进展  

Research progress on low⁃cost ligand⁃based metal⁃organic frameworks for carbon dioxide capture from industrial flue gas

作　　者：江梦珍 王倩 白俊峰 JIANG Mengzhen;WANG Qian;BAI Junfeng(Jiangsu Provincial University Key Laboratory of Intelligent Medical Sensing Materials and Devices,School of Chemistry and Molecular Engineering,Nanjing Tech University,Nanjing 211816,China;State Key Laboratory of Coordination Chemistry,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210093,China)

机构地区：[1]南京工业大学化学与分子工程学院,江苏省智能医用传感材料与器件重点实验室,南京211816 [2]南京大学化学化工学院,配位化学国家重点实验室,南京210093

出　　处：《无机化学学报》2025年第1期1-13,共13页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.22271150);南京大学配位化学国家重点实验室开放课题(No.SKLCC2408)资助。

摘　　要：利用高效绿色材料捕获CO_(2)有助于减少人为向大气中排放CO_(2)。目前,面向工业烟道气CO_(2)捕获的高性能金属有机骨架(MOF)材料的设计与合成研究已步入应用驱使的新阶段。研发和制备具有优越综合性能的CO_(2)捕获MOF材料是一项重要挑战。本综述重点关注面向工业烟道气CO_(2)捕获的基于廉价配体MOF材料的研究现状,总结并讨论了其结构、水/热/化学稳定性、吸附量与选择性、吸附能力受湿气的影响、多轮循环使用性、再生性及宏量制备等性能。Using efficient and green materials to capture carbon dioxide will be beneficial to reducing artificial emissions of carbon dioxide into the atmosphere.The design and synthesis of high‑performance metal‑organic frameworks(MOFs)for capturing carbon dioxide from flue gas has entered a new stage driven by the application.Developing MOFs for carbon dioxide capture with superior comprehensive performance is challenging.This review focuses on the current research on such MOFs with low‑cost ligands.Furthermore,their structures,water/thermal/chemical stability,adsorption capacity and selectivity,adsorption behaviors affected by moisture,multi‑cycle usability,regeneration,and macroscopic preparation were discussed.

关 键 词：廉价配体 金属有机骨架 CO_(2)捕获 综合性能 

分 类 号：O614[理学—无机化学] O613.71[理学—化学]