导电金属有机框架材料的研究进展  

Research progress of conductive metal⁃organic frameworks

作　　者：董晓放 杨悦 王深 郝晓方 王玉霞 程鹏[1] DONG Xiaofang;YANG Yue;WANG Shen;HAO Xiaofang;WANG Yuxia;CHENG Peng(College of Chemistry,Nankai University,Tianjin 300071,China;College of Chemistry,Tianjin Normal University,Tianjin 300387,China)

机构地区：[1]南开大学化学学院,天津300071 [2]天津师范大学化学学院,天津300387

出　　处：《无机化学学报》2025年第1期14-34,共21页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.22435002,21973049);天津师范大学高端人才支持基金资助。

摘　　要：金属有机框架材料是一类具有高比表面积的无机-有机杂化晶态材料,传统的金属有机框架材料由于其导电性较差,在电子器件领域的应用受到限制。近期研究表明,通过引入含有特定共轭结构的配体以增强其导电性等设计策略,能够成功制备出具有较高导电性的金属有机框架材料,从而拓展了其应用范围。本文系统总结了导电金属有机框架材料的设计策略、表征方法、研究进展以及其最新应用,并详细探讨了该研究领域中存在的挑战及其未来的发展方向。Metal‑organic frameworks are porous crystalline materials with a high specific surface area.The poor electrical conductivity of the traditional metal‑organic frameworks limits their applications on electrical devices.Recent studies have shown that metal‑organic framework materials with high electrical conductivity can be prepared by utilizing design strategies such as ligands containing specific conjugated structures,and further to expand their applications.Herein,the design strategies,characterization methods,the latest research progress,and applications of conductive metal‑organic frameworks have been summarized,and the existing problems and potential tendencies are looked ahead to in this article as well.

关 键 词：无机-有机杂化材料 导电金属有机框架 导电性 

分 类 号：TB333[一般工业技术—材料科学与工程] TB34