环三藜芦烃金属配合物的合成、表征及荧光性能研究  

Synthesis,Characterization and Fluorescence Properties of Metal Complexes of Cyclododecane

作　　者：康大伟[1] 高红梅[1] 赵新宇 徐宁[1] KANG Dawei;GAO Hongmei;ZHAO Xinyu;XU Ning(College of Chemistry and Materials Science,Inner Mongolia Key Laboratory of National Products Chemistry and Functional Molecules Synthesis,Inner Mongolia Minzu University,Inner Mongolia Tongliao 028000,China)

机构地区：[1]内蒙古民族大学化学与材料学院,内蒙古自治区天然产物化学与功能分子合成重点实验室,内蒙古通辽028000

出　　处：《广州化工》2025年第1期34-38,共5页GuangZhou Chemical Industry

基　　金：内蒙古自治区教育厅自然科学项目(NJZY21433);内蒙古民族大学科学研究项目(KYQD19036 NMDYB20034)。

摘　　要：利用配体前体HECTV(5,6,12,13,19,20-六咪唑-乙氧基环三藜芦烃)与Zn(CH_(3)COO)_(2)·4H_(2)O、Cd(CH_(3)COO)_2·4H_(2)O、H_(2)bdc(间苯二甲酸)和OH-H_(2)bdc(5-羟基间苯二甲酸),通过优化反应温度、溶剂等因素,自组装合成了三个结构新颖的化合物。[Zn_(6)(HECTV)(bdc)_5(HCOO)_(2)]·4DMF·2H_(2)O(1),[Cd_(3)(HECTV)(bdc)_(3)]·6.5H_(2)O(2),[Cd_(3)(HECTV)(OH-bdc)_(2)(H_(2)O)_(2)]·DMF·2H_(2)O(3)。化合物1~3展示了不同的二维或者三维的结构。有机羧酸配体的差异导致合成的配合物结构变化很大。此外,我们研究了化合物1~3的发光性质。Three structurally novel compounds were synthesized by self-assembly using the ligand precursor HECTV(5,6,12,13,19,20-hexaimidazol-ethoxycyclohexene)with Zn(CH_(3)COO)_(2)·4H_(2)O,Cd(CH_(3)COO)_(2)·4H_(2)O,H_(2) bdc(isophthalic acid),and OH-H_(2) bdc(5-hydroxyisophthalic acid)by optimizing reaction temperature,solvent,and other factors.[Zn_(6)(HECTV)(bdc)5(HCOO)_(2)]·4DMF·2H_(2)O(1),[Cd 3(HECTV)(bdc)3]·6.5H_(2)O(2),[Cd 3(HECTV)(OH bdc)2(H_(2)O)_(2)]·DMF·2H_(2)O(3).Compounds 1 to 3 exhibited different two-dimensional or three-dimensional structures.The differences in organic carboxylic acid ligands led to significant structural changes in the synthesized complexes.In addition,the luminescent properties of compounds 1 to 3 were investigated.

关 键 词：环三藜芦烃 配合物 合成 荧光 

分 类 号：O633[理学—高分子化学]