分子间相互作用对高效催化合成体系的影响及其调控机制  

Influence of Intermolecular Interactions on Efficient Catalytic Synthesis Systems and Their Regulatory Mechanisms

作　　者：李晓鹏[1] 鞠春红[1] 王天亮[2] 姜洋[3] Li Xiaopeng;Ju Chunhong;Wang Tianliang;Jiang Yang(Institute of Petrochemistry,Heilongjiang Academy of Sciences,Harbin 150040,China;Heilongjiang Academy of Sciences,Harbin 150001,China;Institute for Advanced Technology of HAS,Harbin 150001,China)

机构地区：[1]黑龙江省科学院石油化学研究院,哈尔滨150040 [2]黑龙江省科学院,哈尔滨150001 [3]黑龙江省科学院高技术研究院,哈尔滨150001

出　　处：《黑龙江科学》2025年第2期66-69,共4页Heilongjiang Science

摘　　要：随着化学工业和学术界对高效催化剂需求的增加,理解和调控其相互作用成为提升催化性能的关键。概述了分子间相互作用的类型及其在催化反应中的作用,探讨了包括范德华力、氢键、静电作用和π-π相互作用在内的各种相互作用对催化剂性能的影响,研究了高效催化合成体系中催化剂的设计原则,分析了分子结构修饰、功能基团引入、温度和溶剂调控等策略对催化活性与选择性及稳定性的优化作用。With the increasing demand for efficient catalysts in the chemical industry and academia,understanding and regulating these interactions has become the key to improving catalytic performance.The study firstly outlines the types of intermolecular interactions and their roles in catalytic reactions,explores the effects of various interactions including van der Waals forces,hydrogen bonds,electrostatic interactions,andπ-πinteractions on catalyst performance.Subsequently,the design principles of catalysts in efficient catalytic synthesis systems are studied,and the optimization effects of strategies,such as molecular structure modification,introduction of functional groups,temperature and solvent regulation on catalytic activity,selectivity and stability,are analyzed.

关 键 词：分子相互作用 催化合成 调控机制 

分 类 号：O621.251[理学—有机化学]