四(三氟膦)镍制备镍产品中杂质去除方法研究  

Study on Removal of Impurities from Ni Products Prepared by Tetrakis(trifluorophosphine) Nickel

作　　者：王晶[1] 周红艳[1] 王珂 姜雪 侯姝[1] WANG Jing;ZHOU Hongyan;WANG Ke;JIANG Xue;HOU Shu(State key laboratory of particle transport and enrichment technology,Nuclear Industry Physical and Chemical Engineering Research Institute,Tianjin 300180,China)

机构地区：[1]核工业理化工程研究院,粒子输运与富集技术全国重点实验室,天津300180

出　　处：《辽宁化工》2024年第12期1824-1828,共5页Liaoning Chemical Industry

基　　金：核工业理化工程研究院专家基金资助项目(项目编号:ZJ-202221)。

摘　　要：通过理论研究和分析检测,探究了以四(三氟膦)镍与氨水为原料制备镍单质中杂质的存在形式、成因以及影响。从两个方面控制主要杂质元素磷元素和碳元素的含量:一是减少或消除反应原料、实验仪器、实验过程中杂质的引入;二是通过后处理工艺除去杂质。通过设计对比实验,确定了控制两种杂质含量的有效方法。Through theoretical research and analysis,the existence forms,causes and effects of impurities in the preparation of nickel from tetrakis(trifluorophosphine) nickel and ammonia were investigated.The contents of phosphorus and carbon should be controlled from two aspects:one is to reduce or eliminate the introduction of impurities in the reaction raw materials,experimental instruments,and experimental processes;the second is to remove impurities through the post-treatment process.The effective methods to control the content of two kinds of impurities were determined by designing comparative experiments.

关 键 词：四(三氟膦)镍 镍 杂质 去除 

分 类 号：TQ016.1[化学工程]