过渡金属磷化物电解海水制氢的研究进展  

Advances on hydrogen production from seawater electrolysis over transition metal phosphides

作　　者：童晓青[1] 陶梅平[1] TONG Xiao-qing;TAO Mei-ping(College of Post and Telecommunication,Wuhan Institute of Engineering,Wuhan 430073,China)

机构地区：[1]武汉工程大学邮电与信息工程学院,湖北武汉430073

出　　处：《现代化工》2025年第2期73-78,共6页Modern Chemical Industry

摘　　要：简要介绍了海水电催化过程的反应机理,包括阴极析氢反应、阳极析氧反应和竞争析氯反应。综述了近年来过渡金属磷化物海水电解催化剂的研究进展,包括元素掺杂、二元金属磷化物和构建过渡金属磷化物异质结等,对未来过渡金属磷化物电解海水制氢的研究做出了展望。The reaction mechanism of the seawater electrocatalysis process is briefly introduced,including cathodic hydrogen evolution reaction,anodic oxygen evolution reaction,and competitive chlorine evolution reaction.Research progress on transition metal phosphide catalysts for seawater electrolysis in recent years is summarized,including element doping,binary metal phosphides,and the construction of transition metal phosphide heterojunctions.It also provides prospects for future research on transition metal phosphide catalyzed seawater electrolysis for hydrogen production.

关 键 词：海水电解 析氢反应 氯化物氧化 过渡金属磷化物 

分 类 号：TQ151.1[化学工程—电化学工业]