Co-hydrothermal carbonization of polystyrene waste and maize stover combined with KOH activation to develop nanoporous carbon as catalyst support for catalytic hydrotreating of palm oil  

作　　者：Napat Kaewtrakulchai Sirayu Chanpee Supachai Jadsadajerm Sutthipoj Wongrerkdee Kanit Manatura Apiluck Eiad-Ua 

机构地区：[1]Biomass Conversion Technology and Bioenergy Research Unit,Kasetsart Agricultural and Agro-Industrial Product Improvement Institute,Kasetsart University,Bangkok 10900,Thailand [2]Department of Chemical Engineering,School of Engineering,King Mongkut’s Institute of Technology Ladkrabang,Bangkok 10520,Thailand [3]Department of Industrial Chemistry,Faculty of Applied Science,King Mongkut’s University of Technology North Bangkok,Bangkok 10800,Thailand [4]Department of Physical and Material Sciences,Faculty of Liberal Arts and Science,Kasetsart University Kamphaeng Saen Campus,Nakhon Pathom 73140 Thailand [5]Department of Mechanical Engineering,Faculty of Engineering at Kamphaeng Saen,Kasetsart University,Kamphaeng Saen Campus,Nakhonpatom 73140,Thailand [6]College of Materials Innovation and Technology,King Mongkut’s Institute of Technology,Bangkok 10520,Thailand

出　　处：《Carbon Resources Conversion》2024年第4期54-69,共16页碳资源转化(英文)

基　　金：support is acknowledged to the Office of the Permanent Secretary,Ministry of Higher Education,Science,Research and Innovation(OPS MHESI),Thailand Science Research and Innovation(TSRI)(grant no.RGNS 65-220).

摘　　要：Plastic waste is massively generated daily from households,mainly as packaging material,causing serious surrounding ecological problems.The development of plastic waste for higher value-added applications instead of landfilling and incineration has received consideration interest in bioenergy and material science research.Herein,a nanoporous carbon support of nickel phosphide catalyst for palm oil hydrotreating was developed from blended polystyrene waste and maize stover via the Co-hydrothermal carbonization(HTC)coupled with the KOH activation process.The Co-HTC parameters,such as temperature,reaction time,and PS percentage,were studied on the properties of co-hydrochar feedstocks for further activation using the Box behnken design.From the comprehensive characterization results,response surface methodology(RSM)results showed that the rising polystyrene proportion significantly exhibited the higher production yield and fixed carbon of co-hydrochar products,an essential characteristic for porous carbon manufacturing.After activation step,the final nanoporous carbon derived from the co-hydrochar(PMPC)exhibited the highest specific surface area of 1033.58 m^(2)/g with total pore volume of 0.45 cm^(3)/g.Moreover,the PCMC-supported nickel phosphide catalysts were successfully synthesized and tested for the catalytic hydrotreating of palm oil as alternative catalyst.The NiP-PMPC catalyst represents an impressive liquid hydrocarbon yield of 74.68% with a high green diesel selectivity of 85.92% at 100% palm oil conversion.The findings of this study might help develop and utilize blended plastic waste and agricultural waste as an alternate catalytic support for various processes in biofuel and biochemical synthesis.

关 键 词：POLYSTYRENE Maize stover Co-hydrothermal carbonization Nanoporous carbon Catalytic hydrotreating 

分 类 号：O64[理学—物理化学]