Free-Radical Polymerization Induced Grafting-to of Polymer Chains onto Aluminum Nanoparticles  

作　　者：Panqi Sun Chenggong Yang Fei Peng Junbo Dang Wentao Wang Daiwu Deng Ning-Ning Zhang Yang Yang Kun Liu 

机构地区：[1]State Key Laboratory of Supramolecular Structure and Materials,College of Chemistry,Jilin University,Changchun,Jilin 130012,China [2]Key Laboratory of High Performance Plastics,Ministry of Education,College of Chemistry,Jilin University,2699 Qianjin Street,Changchun,Jilin 130012,China

出　　处：《Chinese Journal of Chemistry》2024年第24期3193-3200,共8页中国化学(英文版)

基　　金：supported by the National Natural Science Foundation of China(21975094,22225203,and 22133002);K.L.also thanks the JLU Science and Technology Innovative Research Team(2021TD-03).

摘　　要：Aluminum nanoparticles(Al NPs)have significant potential applications in various fields due to their unique LSPR.Significant advancements have been achieved in controlling the size and morphology of Al NPs.However,the efficient modification of Al NPs with polymers has not been implemented.Herein,we report a facile and efficient free-radical polymerization induced grafting-to(FRPIGt)method for grafting polymer chains onto Al NPs.By optimizing polymerization conditions,we were able to achieve a polymer brush layer with a weight loss fraction of up to 43.3%,which was higher than those of other polymers with carboxyl or primary amine end groups.Moreover,a broad range of vinyl monomers,including styrene,methacrylate,and methyl methacrylate,can be applied using the FRPIGt method to modify Al NPs.In addition,the FRPIGt method can be extended to photoinduced organocatalyzed atom-transfer-radical polymerization.This work paves a new path for the preparation of a wide range of polymer-functionalized Al NPs and their polymer composites to be utilized in various fields.

关 键 词：NANOPARTICLES POLYMERIZATION Aluminum nanoparticle Graft-to FRPIGt Free-radical polymerization POLYSTYRENE O-ATRP 

分 类 号：O63[理学—高分子化学]