Catalytic Cycloaddition Reactions of Ynol and Thioynol Ethers  

作　　者：Ming-Yu Teng Yin Xu Xin-Qi Zhu Bo Zhou Long-Wu Ye 

机构地区：[1]College of Chemistry and Chemical Engineering,Yunnan Normal University,Kunming,Yunnan 650500,China [2]Key Laboratory of Chemical Biology of Fujian Province,State Key Laboratory of Physical Chemistry of Solid Surfaces,and College of Chemistry and Chemical Engineering,Xiamen University,Xiamen,Fujian 361005,China [3]State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China

出　　处：《Chinese Journal of Chemistry》2024年第24期3469-3483,共15页中国化学(英文版)

基　　金：the National Natural Science Foundation of China(22125108,22331004 and 22121001);Yunnan Normal University,and Applied Basic Research Projects of Yunnan Province(202101AT070217).

摘　　要：Electron-rich alkynes,such as ynol and thioynol ethers,have proven to be versatile and appealing partners in catalytic cycloaddition reactions,and thus have raised considerable attentions owing to the practical application in the modular assembly of valuable carbo-and heterocycles.The past decades have witnessed inspiring advances in this emerging field,and an increasing number of related discoveries have been exploited.Divided into two main sections on the basis of substrate type,in each section this comprehensive review will initially summarize their synthetic preparations and subsequently examine their reactivity in every sort of catalytic cycloaddition with emphasis on the methodology development,aimed at providing an access to this burgeoning area and encouraging further innovations in the near future.

关 键 词：Ynol ether Thioynol ether CYCLOADDITION Cyclic molecules Homogeneous catalysis 

分 类 号：O62[理学—有机化学]