Metal-backboned polymer:concept,advance and perspective  

金属主链高分子:概念、进展与展望

作　　者：Yifeng Zhang Kaiwen Zeng Huisheng Peng 张义锋;曾凯雯;彭慧胜(State Key Laboratory of Molecular Engineering of Polymers,Department of Macromolecular Science,Institute of Fiber Materials and Devices,and Laboratory of Advanced Materials,Fudan University,Shanghai 200438,China)

机构地区：[1]State Key Laboratory of Molecular Engineering of Polymers,Department of Macromolecular Science,Institute of Fiber Materials and Devices,and Laboratory of Advanced Materials,Fudan University,Shanghai 200438,China

出　　处：《Science China Materials》2025年第1期105-109,共5页中国科学(材料科学)(英文版)

基　　金：supported by Ministry of Science and Technology of the People’s Republic of China(MOST,2022YFA1203001 and 2022YFA1203002);National Natural Science Foundation of China(22105045,T2321003,22335003);Science and Technology Commission of Shanghai Municipality(21511104900)。

摘　　要：Materials are generally categorized as three main types of metal,non-metal and organic polymer.Among them,metal and organic polymers show opposite advantages and disadvantages.For instance,a metal exhibits both high mechanical strength and electrical conductivity while both low flexibility and solution processibility;an organic polymer exhibits both high flexibility and solution processibility but with both low mechanical strength and electrical conductivity[1–4].Although a lot of efforts are made to synthesize metal/polymer composite materials to partly maintain advantages of each component[5–7],people have never thought that it is possible to achieve the advantages of both metal and polymer by synthesizing novel material with a single component.金属主链高分子是一类完全以金属原子作为主链的新材料,有望在材料领域开创出一个全新的研究领域.本文重点介绍了金属主链高分子的概念、合成、结构、性能与应用情况,诠释了金属主链高分子广阔的发展前景.本文也总结介绍了金属主链高分子在发展过程中面临的挑战和未来的发展方向.

关 键 词：POLYMER BACKBONE CONDUCTIVITY 

分 类 号：TB30[一般工业技术—材料科学与工程]