碳纳米材料在锌离子电池中的应用研究进展  

Advances in the application of carbon nanomaterials for zinc ion batteries

作　　者：徐子易 席阳 宋泽文 周海骏[1] XU Ziyi;XI Yang;SONG Zewen;ZHOU Haijun(School of Materials Science and Engineering,Jiangsu University of Science and Technology,Zhenjiang 212100,Jiangsu,China)

机构地区：[1]江苏科技大学材料科学与工程学院,江苏镇江212100

出　　处：《化工学报》2025年第1期40-52,共13页CIESC Journal

基　　金：国家自然科学基金项目(51903111)。

摘　　要：锌离子电池(ZIBs)由于其低廉的价格、优异的储能性能和安全性能,在电网和可穿戴设备中有很大的发展潜力。但锌作为负极表现出不稳定性,在锌负极上容易形成锌枝晶并伴随析氢和副反应,这一直是其广泛应用的障碍。碳纳米材料具有优异的导电性、化学稳定性和表面性能可调性,在锌离子电池的应用中展现出了广泛的前景。首先简述了锌离子电池的工作原理,重点综述了碳纳米材料在锌离子电池中的应用,最后总结了碳纳米材料在锌离子电池中的不同应用形式及其在电池性能提升方面的作用,并展望了碳纳米材料未来在锌离子电池领域的潜在发展趋势。Zinc ion batteries have great potential for development in power grid and wearable devices due to their low price,excellent energy storage performance,and safety.However,zinc as a negative electrode is unstable,and zinc dendrites are easily formed on the zinc negative electrode accompanied by hydrogen evolution and side reactions,which has always been an obstacle to its widespread application.Carbon nanomaterials with excellent electrical conductivity,chemical stability and tunable surface properties have shown a wide range of applications in zinc ion batteries.This paper first briefly describes the working principle of zinc-ion batteries,and focuses on the application of carbon nanomaterials in zinc ion batteries,then summarizes the different forms of carbon nanomaterials used in zinc ion batteries and their effects on improving battery performance.It also looks forward to the potential future trends of carbon nanomaterials in the field of zinc ion batteries.

关 键 词：碳纳米材料 锌离子电池 电化学 锌负极 碳纳米管 石墨烯 

分 类 号：TQ127.1[化学工程—无机化工]