Recent advances in metal-loaded MOFs photocatalysts:From single atom,cluster to nanoparticle  

作　　者：Shenglan Zhou Haijian Li Hongyi Gao Ang Li Tian Li Shanshan Cheng Jingjing Wang Jitti Kasemchainan Jianhua Yi Fengqi Zhao Wengang Qu 

机构地区：[1]Advanced Innovation Center for Materials Genome Engineering,Beijing Key Laboratory of Function Materials for Molecule&Structure Construction,School of Materials Science and Engineering,University of Science and Technology Beijing,Beijing 100083,China [2]National Key Laboratory of Energetic Materials,Xi’an Modern Chemistry Research Institute,Xi’an 710065,China [3]Shunde Innovation School,University of Science and Technology Beijing,Shunde 528399,China [4]School of Materials Science and Engineering,Suzhou University of Science and Technology,Suzhou 215009,China [5]Department of Chemical Technology,Chulalongkorn University,Bangkok 10330,Thailand

出　　处：《Chinese Chemical Letters》2025年第1期68-79,共12页中国化学快报(英文版)

基　　金：supported by the Beijing Natural Science Foundation(No.L233011);Guangdong Province Natural Science Foundation(No.2022A1515011918);USTB Research Center for International People-to-People Exchange in Science.Technology and Civilization(No.2023KFYB003)。

摘　　要：Photocatalysis is widely regarded as a highly promising sustainable technique for addressing the challenges posed by environmental pollution and energy provision.In recent years,metal-loaded MOFs has become a rising star within the domain of photocatalysis due to its high specific surface area and porosity,adjustable structure,diverse and abundant catalytic components,which has exhibited excellent photocatalytic activity and exhibit great potential in a range of disciplines.In this paper,the principles for evaluating the photocatalytic performance of MOFs-based materials were firstly introduced,and some typical examples were also listed accordingly.Along with this,particular emphasis is paid to the main factors affecting the photocatalytic performance of metal-loaded MOFs.Then the synthesis and design strategies of MOFs loaded metal entities of varying sizes(single atoms,nanoclusters,and nanoparticles),and their applications in photocatalytic CO_(2)reduction,hydrogen production,photooxidation and photocatalytic hydrogenation were summarized and discussed.Finally,the opportunities and challenges faced in this kind of MOFs-based composites were analyzed from different perspectives.This report is expected to help researchers design and develop high-performance MOFs-based photocatalytic materials.

关 键 词：Metal-loaded MOFs Photocatalysis Single atom catalysts NANOCLUSTERS Nanoparticles 

分 类 号：O64[理学—物理化学]