固体氧化物燃料电池用甲醇水蒸气重整反应器研究进展  

Research progress on methanol steam reforming reactors for SOFC

作  者:胡洋 韩传军[1] 胡强 李汶颖 安全成 苏洋 武洪松 袁果 HU Yang;HAN Chuanjun;HU Qiang;LI Wenying;AN Quancheng;SU Yang;WU Hongsong;YUAN Guo(School of Mechanical Engineering,Southwest Petroleum University,Chengdu 610500,Sichuan,China;Zhejiang Zhentai Energy Technology Company Limited,Lishui 323000,Zhejiang,China;Sichuan Energy Internet Research Institute,Tsinghua University,Chengdu 610500,Sichuan,China;Drilling and Production Engineering Technology Research Institute of CNPC Chuanqing Drilling Engineering Company Limited,Xi’an 710018,Shaanxi,China;China Petroleum Great Wall Drilling Engineering Technology Research Institute,Panjin 124010,Liaoning,China;Zhongjing Cloud Data Storage Technology(Beijing)Company Limited,Beijing 100107,China)

机构地区:[1]西南石油大学机电工程学院,四川成都610500 [2]浙江臻泰能源科技有限公司,浙江丽水323000 [3]清华四川能源互联网研究院,四川成都610500 [4]中国石油集团川庆钻探工程有限公司钻采工程技术研究院,陕西西安710018 [5]中国石油长城钻探工程技术研究院,辽宁盘锦124010 [6]中经云数据存储科技(北京)有限公司,北京100107

出  处:《化工进展》2025年第1期169-183,共15页Chemical Industry and Engineering Progress

基  金:国家资助博士后研究人员计划(GZC20241424);浙江省重点研发计划(2021C01100);浙江省领军型创新创业团队(2020R02015)。

摘  要:固体氧化物燃料电池分布式热电联供技术是建设“清洁、低碳、安全、高效”现代能源体系、提高能源供给、保障能源消费安全的重要途径。氢是固体氧化物燃料电池最主要且最适合的燃料,然而,固体氧化物燃料电池分布式热电联供技术的应用受限于氢储运技术的发展。采用液态甲醇作为储氢载体现场重整制氢,有望在氢源供应问题上实现突破。为研究国内外固体氧化物燃料电池用甲醇水蒸气重整反应器进展,本文概述了氢源供应方式,着重总结了现场重整制氢的核心设备——甲醇水蒸气重整反应器的结构功能和供热方式,分析了影响反应器重整性能的操作参数和结构参数,并介绍了甲醇水蒸气重整反应器与固体氧化物燃料电池集成发电的特点,提出固体氧化物燃料电池用甲醇水蒸气重整反应器未来发展方向包括大功率甲醇水蒸气重整反应器的设计、大功率甲醇水蒸气重整反应器制氢机理及传热传质特性研究,以及采用甲醇水蒸气重整反应器直接为中温固体氧化物燃料电池供氢发电的性能。Distributed cogeneration of heat and electricity using solid oxide fuel cells(SOFC)is an important method in building a“clean,low-carbon,safe,and efficient”modern energy system to improve energy supply and ensure energy consumption security.Hydrogen is the most important and most suitable fuel for SOFC.However,the application of SOFC in distributed cogeneration scenario is limited by the challenges in hydrogen storage and transportation technology,which has high cost and significant safety hazards.Using liquid methanol as a hydrogen storage carrier for on-site reforming to produce hydrogen is expected to achieve a breakthrough in the hydrogen supply of SOFC in distributed cogeneration scenario.In this paper,the progress of methanol steam reforming reactor for SOFC at home and abroad are introduced.The hydrogen source supply mode is outlined.And the structure,function and heating mode of methanol steam reforming reactor,which is the core equipment for on-site hydrogen production through reforming,have been summarized.The operation parameters and structural parameters affecting the reforming performance of the reactor are analyzed.And the characteristics of the integrated system of reactor and SOFC are introduced.The future development directions of methanol steam reforming reactor for SOFC include the design of high-power methanol steam reforming reactor,the study of hydrogen production mechanism and the heat and mass transfer characteristics of high-power methanol steam reforming reactor,and the performance of using methanol steam reforming reactor to directly supply hydrogen for medium temperature solid oxide fuel cells to generate power.

关 键 词:燃料电池 化学反应器  甲醇水蒸气重整 分布式热电联供 

分 类 号:TQ05[化学工程]

 

参考文献:

正在载入数据...

 

二级参考文献:

正在载入数据...

 

耦合文献:

正在载入数据...

 

引证文献:

正在载入数据...

 

二级引证文献:

正在载入数据...

 

同被引文献:

正在载入数据...

 

相关期刊文献:

正在载入数据...

相关的主题
相关的作者对象
相关的机构对象