Tailoring directional chiral emission from molecules coupled to extrinsic chiral quasi-bound states in the continuum  

作　　者：MINPENG LIANG LUCIO CLAUDIO ANDREANI ANTON MATTHIJS BERGHUIS JOSÉLUIS PURA SHUNSUKE MURAI HONGGUANG DONG JOSÉASÁNCHEZ-GIL JAIME GÓMEZ RIVAS 

机构地区：[1]Department of Applied Physics and Science Education,Institute for Complex Molecular Systems,and Eindhoven Hendrik Casimir Institute,Eindhoven,5600 MB,The Netherlands [2]Dipartimento di Fisica,Universitàdi Pavia,27100 Pavia,Italy [3]Instituto de Estructura de la Materia(IEM),Consejo Superior de Investigaciones Cientı´ficas,28006 Madrid,Spain [4]GdS-Optronlab,Fı´sica de la Materia Condensada,Universidad de Valladolid,47011 Valladolid,Spain [5]Department of Material Chemistry,Graduate School of Engineering,Kyoto University,Kyoto 615-8510,Japan [6]Centre for Optical and Electromagnetic Research,National Engineering Research Center for Optical Instruments,Zhejiang University,Hangzhou 310027,China

出　　处：《Photonics Research》2024年第11期2462-2473,共12页光子学研究(英文版)

基　　金：Funded by the European Union(SCOLED Grant Agreement Number 101098813);Funded by the Dutch Organization for Scientific Research(NWO)through the Gravitation Grant Research Centre for Integrated Nanophotonics;financial support from Italian MUR through PNRR project PE0000023-NQSTI;financial support from Spanish Ministerio de Ciencia,Innovación y Universidades and Agencia Estatal de Investigación(MCIN/AEI/10.13039/501100011033);the financial support from NextGenerationEU(CONVREC-2021-23);financial support from the Bilateral Joint Research Project(JPJSBP120239921)from Japan Society for the Promotion of Science;financial support from the China Scholarship Council(CSC202206320284)。

摘　　要：We investigate the chiral emission from non-chiral molecules coupled to metasurfaces with a unit cell formed by dimers of detuned and displaced Si nanodisks.The detuning and displacement lead to the formation of narrow modes,known as quasi-bound states in the continuum(Q-BICs),with different electric and magnetic characteristics.The dispersion and character of the modes are explained by using the guided-mode expansion method and finite-element simulations.The coupling between these modes leads to an extrinsic chiral response with large circular dichroism for defined energies and wavevectors.When the lattice constant of the metasurface is changed,the dispersion of the extrinsic chiral Q-BICs can be tuned and the emission properties of a thin film of dye molecules on top of the metasurface are modified.In particular,we observe strongly directional and circularly polarized emission from the achiral dye molecules with a degree of circular polarization reaching 0.8 at the wavelengths defined by the dispersion of the Q-BICs.These results could enable the realization of compact light sources with a large degree of circular polarization for applications in displays,optical recording,or optical communication.

关 键 词：CHIRAL circular QUASI 

分 类 号：O62[理学—有机化学]