Lignin-impregnated biochar assisted with microwave irradiation for CO_(2)capture:adsorption performance and mechanism  

作　　者：Xueyang Zhang Haoliang Xu Wei Xiang Xinxiu You Huantao Dai Bin Gao 

机构地区：[1]School of Environmental Engineering,Xuzhou University of Technology,Xuzhou 221018,China [2]Department of Civil and Environmental Engineering,Rensselaer Polytechnic Institute,Troy,NY 12180,USA.

出　　处：《Biochar》2024年第1期354-367,共14页生物炭(英文)

基　　金：from Natural Science Foundation of Jiangsu Province(BK20201151);Science and Technology Plan Projects of Xuzhou(KC21288).

摘　　要：Bamboo biochar was modified by lignin impregnation and microwave irradiation to enhance its performance for CO_(2)capture.The pore structure of lignin-impregnated biochar was significantly affected by the impregnation ratio.The maximum specific surface area of 377.32 m^(2)g^(−1)and micropore volume of 0.163 cm^(3)g^(−1)were observed on the biochar with an impregnation ratio of 1:20(mass ratio of lignin to biochar).Lignin impregnation increased the CO_(2)adsorption capacity of biochar up to 134.46 mg g^(−1).Correlation analysis confirmed the crucial role of biochar’s pore structure in adsorption.The Avrami model fitted the CO_(2)capture curves well.The calculation of adsorption activation energy suggested that the adsorption process was dominated by physical mechanism assisted with partial chemical mechanism.Meanwhile,Langmuir isotherm analysis indicated that lignin impregnation transformed the larger pores of biochar into more uniform micropores,thereby making the adsorption process closer to monolayer adsorption.Both the high reusability(89.79-99.06%)after 10 successive cycles and the excellent CO_(2)selectivity in competitive adsorption confirmed that lignin-impregnated biochar is an outstanding adsorbent for CO_(2)capture.

关 键 词：BIOCHAR Lignin impregnation Microwave irradiation CO_(2)capture 

分 类 号：S15[农业科学—土壤学]