不同溶剂中原子转移自由基聚合反应的动力学研究进展  

Research Progress in Kinetics of Atom Transfer Radical Polymerization Reaction in Different Solvent

作　　者：黎水娟 王懿明 王运楠 韩向艳 雷良才 李海英 LI Shuijuan;WANG Yiming;WANG Yunnan;LEI Liangcai;LI Haiying(School of Petrochemical Engineering,Liaoning Petrochemical University,Fushun Liaoning 113001,China)

机构地区：[1]辽宁石油化工大学石油化工学院,辽宁抚顺113001

出　　处：《当代化工》2025年第1期138-144,共7页Contemporary Chemical Industry

基　　金：国家自然科学基金项目(项目编号:21544008)。

摘　　要：原子转移自由基聚合是一种新型的可控聚合方法,在可控合成领域中具有重要作用。介绍了原子转移自由基聚合的反应机理、CuIX催化体系中不同结构配体对聚合反应的影响,并综述了不同溶剂(如水、醇/水、环己酮、N,N-二甲基甲酰胺和二甲苯)体系中原子转移自由基聚合反应动力学研究的进展。Atom transfer free radical polymerization is a novel controllable polymerization method that plays an important role in the field of controlled synthesis.In this article,the reaction mechanism of atom transfer free radical polymerization was introduced,as well as the influence of different structural ligands in CuIX catalytic system on the polymerization reaction,and the research progress of atom transfer free radical polymerization kinetics in different solvent systems(such as water,alcohol/water,cyclohexanone,N,N-dimethylformamide and xylene)was reviewed.

关 键 词：原子转移自由基聚合反应 配体 可控聚合 聚合反应动力学 

分 类 号：TQ316.322[化学工程—高聚物工业]