超临界流体技术制备超细含能材料的研究进展  

Research Progress in Preparation of Ultrafine Energetic Materials by Supercritical Fluid Technology

作　　者：刘超 丁亚军 常圣泉 王浩 刘少武[1,2] 孔军利 LIU Chao;DING Yajun;CHANG Shengquan;WANG Hao;LIU Shaowu;KONG Junli(Liaoning Qingyang Chemical Industry Corporation,Liaoyang Liaoning 111000,China;Xi’an Modern Chemistry Research Institute,Xi’an Shaanxi 710065,China)

机构地区：[1]辽宁庆阳特种化工有限公司,辽宁辽阳111000 [2]西安近代化学研究所,陕西西安710065

出　　处：《当代化工》2025年第1期159-163,219,共6页Contemporary Chemical Industry

基　　金：国家自然科学基金项目(项目编号:2220090187)。

摘　　要：超临界流体技术在含能材料细化方面应用广泛,其作为未来军事技术优势的关键技术得到世界各国的高度关注。为了拓宽含能材料的应用范围,提升武器系统的毁伤能力,并为含能材料细化领域的研究提供借鉴,综述了超临界流体技术在超细含能材料制备方面的原理、工艺过程及研究进展。首先,归纳梳理了超临界流体的物理特性,并对其工艺特点和适用条件进行了分析;其次,详细探究了超临界流体技术在含能材料细化中的应用,并阐述了影响晶体形貌和粒径分布的主要因素;最后,从理论研究、工艺流程和工业应用等角度提出当前限制超临界流体技术在含能材料细化领域进一步发展的主要因素,并对超临界流体技术在含能材料细化领域的发展提出展望。Supercritical fluid technology is widely applied in the refinement of energetic materials,which has also been highly concerned by many countries as a key technology of future military technological advantage.In order to broaden the scope of application of energetic materials,enhance the destructive capability of weapon systems,and provide the reference for the research in the field of energetic materials,the principle,process and research progress of supercritical fluid technology in the preparation of ultrafine energetic materials were reviewed.First,the physical properties of supercritical fluids were summarized,their process characteristics and applicable conditions were also analyzed.Second,the application of supercritical fluid technology in the refinement of energetic materials was explored in detail,and the main factors affecting the crystal morphology and particle size distribution were elaborated.At last,the main factors limiting the further development of supercritical fluid technology in the field of ultrafine-energetic materials were proposed from the perspectives of theoretical research,process flow and industrial applications,and the prospect of supercritical fluid technology in the field of ultrafine energetic materials was also presented.

关 键 词：超临界流体 含能材料 细化 晶体形貌 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术]