共价三嗪骨架储锂性能研究融入材料综合实验教学  

Research on Lithium Storage Performance of Covalent Triazine Skeleton Incorporating into Comprehensive Experimental Teaching of Materials

作　　者：于延新 金倩倩 亓敬波 张临财 任衍彪 YU Yanxin;JIN Qianqian;QI Jingbo;ZHANG Lincai;REN Yanbiao(College of Chemistry,Chemical Engineering and Material Science,Zaozhuang University,Shandong Zaozhuang 277160,China)

机构地区：[1]枣庄学院化学化工与材料科学学院,山东枣庄277160

出　　处：《广州化工》2025年第3期192-195,共4页GuangZhou Chemical Industry

基　　金：枣庄学院教学改革研究重点项目;教育部产学合作协同育人项目(202102404013、220605877135952);山东省高等学校青创科技计划创新团队(2021KJ057)

摘　　要：以有机储能为代表的“绿色储能”技术有望突破资源与环境对能源发展的制约。共价三嗪骨架(CTFs)材料能够将储锂位点精准地构筑到其结构中,其被认为是最具发展潜力的绿色储能材料。在科学研究的基础上,本实验创新设计了一个材料综合实验。以商品化的三聚氰胺作为原料通过溶剂热方法制备了一种偶氮功能性CTF(Azo-CTF)电极材料。利用红外光谱、X-射线衍射、扫描电镜等表征技术对Azo-CTF的结构进行解析,并进一步将其用于锂离子电池性能研究。本实验不仅能够培养学生制备有机电极材料的技能,还能够进一步促进学生了解储能领域科学前沿,提升学生的科学素养与创新意识。The“green energy storage”technology represented by organic energy storage is expected to break through the constraints of resources and environment on energy development.Covalent triazine frameworks(CTFs)materials can accurately construct lithium storage sites into their structures,and are considered the most promising green energy storage materials.On the basis of scientific research,this experiment innovatively designed a comprehensive material experiment.An azo functional CTF(Azo-CTF)electrode material was prepared by solvothermal method using commercialized melamine as raw material.The structure of Azo-CTF was analyzed using characterization techniques such as infrared spectroscopy,X-ray diffraction,and scanning electron microscopy,and further applied to the study of lithium-ion battery performance.This experiment can not only cultivate students skills in preparing organic electrode materials,but also further promote their understanding of the scientific frontiers in the field of energy storage,enhance their scientific literacy and innovation awareness.

关 键 词：有机储能 共价三嗪骨架 创新实验 锂离子电池 

分 类 号：O614.12[理学—无机化学]