生物质含氧衍生物可控转化制备功能化学品  

Controllable conversion of biomass-derived oxygenates to synthesize functional chemicals

作　　者：肖成雷 梁孔乾 张文礼 宋金良 韩布兴[2] Chenglei Xiao;Kongqian Liang;Wenli Zhang;Jinliang Song;Buxing Han(School of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou 510006,China;Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China)

机构地区：[1]广东工业大学轻工化工学院,广州510006 [2]中国科学院化学研究所,北京100190

出　　处：《中国科学:化学》2025年第1期18-27,共10页SCIENTIA SINICA Chimica

基　　金：国家重点研发计划(编号:2023YFB4203603);国家自然科学基金(编号:22372043,22072157)资助项目。

摘　　要：生物质是储量最丰富的可再生有机碳资源.充分利用生物质替代化石资源制备高值化学品或燃料有助于缓解资源短缺、环境污染等问题.其中,生物质含氧衍生物选择性转化是生物质转化领域的重要研究内容,能够极大增加生物质基化学品及燃料的种类,已经得到研究者的高度关注.本文总结了课题组近年来在生物质含氧衍生物可控转化制备功能分子方面的研究进展,主要包括生物质含氧衍生物加氢/氢解反应、生物质含氧衍生物还原胺化反应、生物质含氧衍生物氧化转化.最后,讨论生物质含氧衍生物可控转化领域存在的关键科学难题及面临的主要挑战,对该领域的发展前景进行了展望.Biomass is the most abundant renewable organic carbon resource.Fully utilization of biomass as an alternative for fossil resources to produce value-added chemicals or fuels can alleviate some challenging issues related with energy/resource shortage and environmental pollution.In this context,selective conversion of biomass-derived oxygenates is an important research topic in the field of biomass conversion,which can greatly increase the types of biomass-based chemicals and fuels.Thereby,conversion of biomass-derived oxygenates into functional chemicals has received gradually increasing attention.In this article,we summarize the progress in our group on the controllable conversion of biomass-derived oxygenates to synthesize functional chemicals in recent years,mainly including hydrogenation/hydrolysis of biomass-derived oxygenates,reductive amination of biomass-derived oxygenates,and oxidative conversion of biomass-derived oxygenates.Finally,we discuss the key scientific problems and the main challenges in the controllable conversion of biomass-derived oxygenates,and analyze the development prospects for this important field.

关 键 词：生物质转化 生物质含氧衍生物 功能化学品 C-C/C-O键催化演变 功能催化材料 

分 类 号：TK6[动力工程及工程热物理—生物能] TQ426[化学工程] TQ072