电化学加氢合成生物质基呋喃类高值化学品的研究进展  

Recent progress in the synthesis of high-value biomass-derived furanic chemicals through electrochemical hydrogenation

作　　者：王宇辰 许镇浩 刘瑶钰 卜婉荣 严凯 Yuchen Wang;Zhenhao Xu;Yaoyu Liu;Wanrong Bu;Kai Yan(School of Environmental Science and Engineering,Sun Yat-Sen University,Guangzhou 510275,China)

机构地区：[1]中山大学环境科学与工程学院,广州510275

出　　处：《中国科学:化学》2025年第1期97-106,共10页SCIENTIA SINICA Chimica

基　　金：国家重点研发项目(编号:2023YFC3905804);国家自然科学基金面上项目(编号:22378434,22078374,21776324);广东省自然科学基金面上项目(编号:2022A1515011150)资助。

摘　　要：呋喃类化合物是一类重要的生物质基平台分子,可通过多种亲电取代反应升级转化为高价值化学品.近年来,电化学加氢合成生物质基呋喃类高值化学品作为一种绿色、经济、高效的催化转化手段受到研究者们的广泛关注,科研工作者们已经在催化剂制备方面和电化学加氢机理研究方面取得了一系列重要进展.本文首先归纳了电化学加氢呋喃类平台化合物的反应路径及机理,随后详细介绍了近年来该催化反应的研究进展,最后对常温常压下实现呋喃类高值化学品的高选择性合成进行了总结和展望.Furanic compounds are an important class of biomass-based platform molecules,which can be upgraded to high-value chemicals through a variety of electrophilic reactions.In recent years,as a green,economical,and efficient catalytic conversion technology,the synthesis of high-value biomass-derived furanic chemicals by electrochemical hydrogenation has attracted extensive attention from researchers.Researchers have made a series of important progress in catalyst preparation and electrochemical hydrogenation mechanism.In this review,the reaction path and mechanism of electrochemical hydrogenation of furanic platform compounds are first elucidated.Afterward,recent research progress in this catalytic reaction is introduced in detail.Finally,the highly selective synthesis of high-value furanic chemicals under room temperature and atmospheric pressure is summarized and prospected.

关 键 词：电化学加氢 生物质 呋喃类 高值化学品 

分 类 号：O62[理学—有机化学]