Advances in the use of biomass-derived carbons for sodium-ion batteries  

用于钠离子电池的生物质衍生炭的研究进展

作　　者：SUN Mei-ci QI Shuo-lin ZHAO Yun-he CHEN Chun-xia TAN Li-chao HU Zhong-li WU Xiao-liang ZHANG Wen-li 孙美慈;祁烁霖;赵芸鹤;陈春霞;谭立超;胡忠利;吴小亮;张文礼(东北林业大学化学化工与资源利用学院合成化学与资源利用创新研究中心,黑龙江哈尔滨1500400;浙江万里学院碳中和研究院,浙江宁波315100;重庆理工大学化学化工学院,重庆400054;广东工业大学轻工与化工学院,广东广州510006;化学与化学工程广东省实验室揭阳中心(榕江实验室),广东揭阳515200;广东工业大学先进制造学院,广东揭阳522000)

机构地区：[1]Center for Innovative Research in Synthetic Chemistry and Resource Utilization,College of Chemistry,Chemical Engineering and Resource Utilization,Northeast Forestry University,Harbin 150040,China [2]Institute of Carbon Neutrality,Zhejiang Wanli University,Ningbo,315100,China [3]College of Chemistry and Chemical Engineering,Chongqing University of Technology,Chongqing 400054,China [4]Guangdong Provincial Key Laboratory of Plant Resources Biorefinery,School of Chemical Engineering and Light Industry,Guangdong University of Technology(GDUT),Guangzhou 510006,China [5]Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory(Rongjiang Laboratory),Jieyang 515200,China [6]School of Advanced Manufacturing,Guangdong University of Technology(GDUT),Jieyang 522000,China

出　　处：《新型炭材料(中英文)》2025年第1期1-49,共49页New Carbon Materials

基　　金：黑龙江省优秀青年基金(YQ2023E002);国家自然科学基金会(32370413,22478083).

摘　　要：Sodium-ion batteries(SIBs)have emerged as a promising alternative to commercial lithium-ion batteries be-cause of the similar properties of Li and Na as well as the abundance and accessibility of sodium resources.The devel-opment of anode materials with a high capacity,excellent rate performance,and long cycle life is the key to the indus-trialization of SIBs.Biomass-derived carbon(BDC)anode materials synthesized from resource-rich,low-cost,and re-newable biomass have been extensively researched and their excellent sodium storage performance has been proven,making them the most promising new low-cost and high-performance anode material for SIBs.This review first intro-duces the sources of BDCs,including waste biomass such as plants,animals,and microorganisms,and then describes sev-eral methods for preparing BDC anode materials,including carbonization,chemical activation,and template methods.The storage mechanism and kinetic process of Na^(+)in BDCs are then considered as well as their structure control.The electrochemical properties of sodium-ion storage in BDCs with different structures are examined,and suggestions for future re-search are made.钠元素具有与锂元素相似的性质,同时钠资源丰富且易于获取,钠离子电池(SIBs)已成为商用锂离子电池的一种有前途的替代品。开发具有高容量、优异倍率性能和长循环寿命的负极材料是钠离子电池产业化的关键。从资源丰富、成本低廉、可再生的生物质中合成的生物质衍生炭(BDCs)负极材料已被广泛研究,并证实其具有优异的储钠性能,有望成为最有前途的新型低成本、高性能SIBs负极材料。本文首先介绍了BDCs的来源,包括植物、动物和微生物等废弃生物质。然后介绍了制备BDCs负极材料的几种方法,包括炭化法、活化法和模板法。随后,分析了BDCs中钠离子的储存机制、动力学以及结构调控工程,还探讨了不同结构的BDCs存储钠的电化学特性。最后,对BDCs负极未来的研究方向进行了展望。

关 键 词：BIOMASS Carbon Anode materials Sodium storage mechanism Microstructure 

分 类 号：TQ127.1[化学工程—无机化工]