超级电容器用聚苯乙烯树脂基碳微球的结构控制及其电化学性能  

Structure Control of Polystyrene Resin-Based Carbon Microspheres as Electrode Materials and Its Supercapacitor Performance

作　　者：王俊博 孙刚伟 张永正[1] 沈春银[1] 王艳莉[1] 詹亮[1] WANG Junbo;SUN Gangwei;ZHANG Yongzheng;SHEN Chunyin;WANG Yanli;ZHAN Liang(State Key Laboratory of Green Chemical Engineering and Industrial Catalysis,State Key Laboratory of Chemical Engineering,Shanghai Key Laboratory of Multiphase Materials Chemical Engineering,East China University of Science and Technology,Shanghai 200237,China;Orinko Advanced Plastics(Shanghai)Co.Ltd,Shanghai 201108,China)

机构地区：[1]华东理工大学绿色化工与工业催化国家重点实验室,化学工程联合国家重点实验室,上海市多相结构材料化学工程重点实验室,上海200237 [2]会通新材料(上海)有限公司,上海201108

出　　处：《华东理工大学学报(自然科学版)》2025年第1期35-41,共7页Journal of East China University of Science and Technology

基　　金：国家自然科学基金(51472086,51002051,22075081,20806024);上海市自然科学基金(12ZR1407200)。

摘　　要：以苯乙烯和二乙烯基苯为原料,石蜡为造孔剂,采用悬浮聚合及后续热处理制得聚苯乙烯树脂基碳微球(PCS)以用作超级电容器电极材料,并对其孔结构、表面形貌及表面化学性质进行了分析。结果表明,当添加质量分数为30%的石蜡造孔剂时,所制聚苯乙烯树脂基碳微球(PCS-30%)的比表面积高达2589 m^(2)/g,其中微孔表面积为2328 m^(2)/g;在Et4NBF4-PC电解液体系下,将该材料作为电极材料制备双电层超级电容器,在0.1 A/g的电流密度条件下,电容器的比电容为106.4 F/g,相应超级电容器的能量密度为22.1 W·h/kg。Polystyrene resin-based carbon microspheres(PCS)were synthesized through suspension polymerization method and followed by heat treatment using styrene and divinylbenzene as raw materials,paraffin wax as pore-forming agent,respectively.The as-prepared PCS were used as the electrode material for a double-layer supercapacitor,and its pore structure,surface morphologies,and chemical properties were analyzed.The results showed that,when paraffin wax of 30%was added to the raw material system,PCS-30%gave a large specific surface area of 2589 m^(2)/g,with a micropore surface area of 2328 m^(2)/g.When used as the electrode material for a double-layer supercapacitor,the obtained electrode material in the organic electrolyte of Et4NBF4-PC exhibited a high specific capacitance of 106.4 F/g and energy density of 22.1 W·h/kg at a current density of 0.1 A/g.

关 键 词：超级电容器 聚苯乙烯树脂基碳微球 悬浮聚合 造孔剂 交联剂 

分 类 号：TQ127.11[化学工程—无机化工]