固体推进剂用含能氧化剂的研究进展  

Research progress on energetic oxidizers in solid propellants

作　　者：王显锋 许元刚 陆明[1] WANG Xianfeng;XU Yuangang;LU Ming(School of Chemistry and Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,China)

机构地区：[1]南京理工大学化学与化工学院,南京210094

出　　处：《固体火箭技术》2025年第1期9-26,共18页Journal of Solid Rocket Technology

基　　金：国家自然科学基金(22475102)。

摘　　要：固体推进剂用含能氧化剂研究主要集中在提高固体推进剂的能量和稳定性,以及开发新型含能氧化剂等方面。为了进一步促进固体推进剂用含能氧化剂的发展,系统综述了不同类型含能氧化剂的研究进展,介绍了各种含能氧化剂相应的物化参数、优缺点及改性研究,重点关注高能量密度氧化剂的最新进展。改善离子型含能氧化剂的配方稳定性、实现共价型含能氧化剂高能与稳定共存仍是一项艰巨的挑战,高能量、高稳定性、多功能性含能氧化剂是未来重要发展方向。研究与各种氧化剂相适配的推进剂配方,对综合性能优异的氧化剂进行路线优化和应用方面的探索,以及通过对构效关系的研究与总结以设计出更多新型含能氧化剂是未来研究的重点。The research on energetic oxidizers for solid propellants primarily focuses on enhancing the energy and stability of solid propellants,as well as developing new energetic oxidizers.To further promote the development of energetic oxidizers for solid propellants,the research progress of different types of energetic oxidizers was systematically reviewed,and the corresponding physicochemical parameters,advantages and disadvantages of various energetic oxidizers and modification studies were introduced,with a particular emphasis on the latest developments in high-energy-density oxidizers.Improving the formulation stability of ionic energetic oxidizers and achieving a coexistence of high energy and stability in covalent energetic oxidizers remain significant challenges.High-energy,high-stability,and multifunctional energetic oxidizers are important future development directions.Studying propellant formulations that are compatible with various oxidizers,optimizing routes and exploring the application of oxidizers with superior comprehensive performance,and designing more new types of energetic oxidizers through the study and summarization of structure-property relationships will be the key focuses of future research.

关 键 词：固体推进剂 含能材料 氧化剂 氧平衡 研究进展 

分 类 号：V512[航空宇航科学与技术—航空宇航推进理论与工程]