农林生物质衍生多孔碳构筑锂电池负极新材料  

New anode materials for lithium batteries constructed from porous carbon derived from agricultural and forestry biomass

作　　者：肖高[1,2,3,4] 郑明珠 毛诗钰 李晓慧 XIAO Gao;ZHENG Mingzhu;MAO Shiyu;LI Xiaohui(College of Environment&Safety Engineering,Fuzhou University,Fuzhou 350108,Fujian,China;Department of Environment and Resources Engineering,Fuzhou University Zhicheng College,Fuzhou 350002,Fujian,China;Fujian Provincial Technology Exploitation Base of Biomass Resources,Fuzhou 350108,Fujian,China;State Key Laboratory of Photocatalysis on Energy and Environment,Fuzhou University,Fuzhou 350108,Fujian,China)

机构地区：[1]福州大学环境与安全工程学院,福建福州350108 [2]福州大学至诚学院环境资源工程系,福建福州350002 [3]福建省生物质资源化技术开发基地,福建福州350108 [4]福州大学能源与环境光催化国家重点实验室,福建福州350108

出　　处：《精细化工》2025年第2期233-243,共11页Fine Chemicals

基　　金：国家级大学生创新创业训练计划重点支持项目(202313470001);福建省自然科学基金面上项目(2022J01564,2017J01412);国家自然科学基金青年项目(21506036);中国博士后科学基金特别资助项目(2020T130599);福州大学贵重仪器设备开放测试基金项目(2023T004)。

摘　　要：农林生物质废弃物作为一种价廉易得的可再生资源,具有丰富的碳源和多孔通道优势。其通过炭化和活化等制备方法及其他复合改性方法可得到具有优良性能的新型多孔材料,该材料在储能方面具有广阔的应用前景。特别是在锂离子电池中的应用方面,生物质衍生多孔碳具备可提高电池的循环性能、容量和倍率性能等优势。该文对基于生物质构建锂离子电池负极材料的应用现状进行了总结,主要介绍了稻壳、玉米秸秆、棉花和果壳等生物质衍生多孔碳应用于锂离子电池负极的电化学性能,并探讨了目前生物质基负极材料存在的问题。另外,还讨论了未来生物质在储能领域的研究方向和应用前景,为化工新型碳材料和锂离子电池的可持续发展提供了新途径和新思路。Agricultural and forestry biomass,a cheap and easily available renewable resource with abundant carbon sources and porous channels,could be used to synthesize new porous chemical materials with excellent properties via carbonization,activation and other composite modification methods.The derived materials has broad application prospects in energy storage,especially in lithium-ion batteries,due to their enhancement in cycle performance,capacity and rate performance of batteries.In this review,the latest research progress and development status of biomass-based anode materials for lithium-ion batteries were summarized,and the electrochemical performance of biomass-based(rice husks,corn straws,cotton and fruit husks,et al)anode materials for lithium-ion batteries was mainly introduced.The existing problems of biomass-based anode materials were also discussed.In addition,the future development direction of biomass in the field of energy storage was prospected to provide new ways and strategies for the synthesis of new carbon materials in chemical industry and the sustainable development of lithium-ion batteries.

关 键 词：生物质衍生多孔碳 锂离子电池 负极材料 农林废弃物 应用方向 

分 类 号：TM912[电气工程—电力电子与电力传动]