Surface ligand-promoted heterogeneous CO_(2) catalysis  

作　　者：Zhe Lu Lu Wang 

机构地区：[1]School of Science and Engineering,The Chinese University of Hong Kong,Shenzhen,Shenzhen 518172,China

出　　处：《Science China Chemistry》2025年第2期444-457,共14页中国科学(化学英文版)

基　　金：supported by the National Key R&D Program of China(2021YFF0502000);the National Natural Science Foundation of China(52102311);the Shenzhen Natural Science Foundation 2022,the Shenzhen Key Laboratory of Eco-materials and Renewable Energy(ZDSYS20200922160400001);the Provincial Talent Plan(2023TB0006);the University Development Fund(UDF01001721).

摘　　要：Heterogeneous CO_(2) catalysis towards the synthesis of high-value products provides a potent pathway for achieving carbon neutrality.The distinctive attributes of surface ligands allow for highly effective tuning of the kinetics and mechanisms to enhance CO_(2) conversion performance.In this review,the catalytic contributions of surface ligands from the view of structure modulation,mechanism modulation,mass transfer,and energy transfer were summarized.The relationships between surface ligands and the performance of functionalized catalysts were further explored.Subsequently,the applications of hydrocarbon chain spacer,hydroxyl and amino as terminal,and SiOx ligand in thermal,photo,and photothermal CO_(2) conversion were investigated.By examining the current limitations and advancements,we concluded with insights into potential future research directions that focus on the development of precisely tuned active sites for highly efficient CO_(2) conversion.

关 键 词：heterogeneous catalysis CO_(2) conversion surface ligands 

分 类 号：X701[环境科学与工程—环境工程] O643.36[理学—物理化学]